Citation:
WANG Mingtai, ZONG Huijuan. POLYMER-SUPPORTED GRIGNARD REAGENT AND ITS USE IN THE FUNCTIONALIZATION OF POLYMER[J]. Chinese Journal of Polymer Science,
1995, 13(1): 84-90.
POLYMER-SUPPORTED GRIGNARD REAGENT AND ITS USE IN THE FUNCTIONALIZATION OF POLYMER
摘要:
Polymeric Grignard Reagent (PGR) based on the chloromethylated poly(ST-co-DVB) resinhas been prepared by means of anthracene-magnesium complex in THF (Anth-Mg-THF), andpolymer matrix with long polymethylene spacer was synthesized via the coupling reaction betweenPGR and α, ω-dibromoalkanes. Based on the studies of factors affecting the coupling, such ascatalyst,reaction time,the length of spacer etc.,this paper offers the optimal reaction conditionsand three typical experiment procedures. The mechanism for the formation and coupling reaction of PGR are also discussed.
English
POLYMER-SUPPORTED GRIGNARD REAGENT AND ITS USE IN THE FUNCTIONALIZATION OF POLYMER
Abstract:
Polymeric Grignard Reagent (PGR) based on the chloromethylated poly(ST-co-DVB) resinhas been prepared by means of anthracene-magnesium complex in THF (Anth-Mg-THF), andpolymer matrix with long polymethylene spacer was synthesized via the coupling reaction betweenPGR and α, ω-dibromoalkanes. Based on the studies of factors affecting the coupling, such ascatalyst,reaction time,the length of spacer etc.,this paper offers the optimal reaction conditionsand three typical experiment procedures. The mechanism for the formation and coupling reaction of PGR are also discussed.
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