Citation:
YAN Wei-Hong, SHEN Ming-Le, JI E-Yu, HUANG Ya-Ping, LIU Xue-Guo. Three Nickel/maleonitriledithiolate Complexes Accompanied by Different Organic Molecules: Syntheses, Crystal Structures and Properties[J]. Chinese Journal of Structural Chemistry,
2015, 34(6): 965-972.
doi:
10.14102/j.cnki.0254-5861.2011-0704
Three Nickel/maleonitriledithiolate Complexes Accompanied by Different Organic Molecules: Syntheses, Crystal Structures and Properties
摘要:
Three complexes [AMP][Ni(mnt)2]·CH3CN (1, AMP=1-(9-anthrylmethyl)pyridinium), [DPI]2[Ni(mnt)2]I (2, DPI=diphenyliodonium) and [DD][Ni(mnt)2]2·2H2O (3, DD=dimethylenediamine) have been prepared and characterized by elemental analyses and IR spectroscopy. X-ray diffraction studies show that three complexes crystallize in the same triclinic space group P1, and anionic accumulations are formed in a column shape. The results show that different counter-cations could induce versatile anionic stacks. The structures of three complexes exhibit rich hydrogen bonding interactions. In addition, UV-VIS properties of them are also investigated.
English
Three Nickel/maleonitriledithiolate Complexes Accompanied by Different Organic Molecules: Syntheses, Crystal Structures and Properties
Abstract:
Three complexes [AMP][Ni(mnt)2]·CH3CN (1, AMP=1-(9-anthrylmethyl)pyridinium), [DPI]2[Ni(mnt)2]I (2, DPI=diphenyliodonium) and [DD][Ni(mnt)2]2·2H2O (3, DD=dimethylenediamine) have been prepared and characterized by elemental analyses and IR spectroscopy. X-ray diffraction studies show that three complexes crystallize in the same triclinic space group P1, and anionic accumulations are formed in a column shape. The results show that different counter-cations could induce versatile anionic stacks. The structures of three complexes exhibit rich hydrogen bonding interactions. In addition, UV-VIS properties of them are also investigated.
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Key words:
- maleonitriledithiolate
- / syntheses
- / crystal structure
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