Syntheses and Crystal Structures of Three Metal Carbonyl Complexes Based on Pyridyl Side Chain Functionalized Tetramethylcyclopentadienyl Ligand

MA Zhi-Hong HAN Ya-Xue WANG Hong HAN Zhan-Gang ZHENG Xue-Zhong LIN Jin

Citation:  MA Zhi-Hong, HAN Ya-Xue, WANG Hong, HAN Zhan-Gang, ZHENG Xue-Zhong, LIN Jin. Syntheses and Crystal Structures of Three Metal Carbonyl Complexes Based on Pyridyl Side Chain Functionalized Tetramethylcyclopentadienyl Ligand[J]. Chinese Journal of Structural Chemistry, 2015, 34(6): 931-937. doi: 10.14102/j.cnki.0254-5861.2011-0639 shu

Syntheses and Crystal Structures of Three Metal Carbonyl Complexes Based on Pyridyl Side Chain Functionalized Tetramethylcyclopentadienyl Ligand

    通讯作者: LIN Jin,
  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (No.21372061) (No.21372061)

    the Key Research Fund of Hebei Normal University (No.L2012Z02) (No.L2012Z02)

摘要: Thermal treatment of the pyridyl side chain functionalized tetramethyl cyclopentadiene C5Me4CH2(C5H4N) with Fe(CO)5, Ru3(CO)12 and Mo(CO)6 in refluxing xylene respectively gave the corresponding dinuclear metal carbonyl complexes 1~3. These complexes have been characterized by elemental analysis, IR and 1H NMR spectra. The molecular structures of 1~3 were determined by X-ray diffraction analysis.

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  • 收稿日期:  2015-01-14
  • 网络出版日期:  2015-04-09
通讯作者: 陈斌, bchen63@163.com
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