Citation:
MA Zhi-Hong, HAN Ya-Xue, WANG Hong, HAN Zhan-Gang, ZHENG Xue-Zhong, LIN Jin. Syntheses and Crystal Structures of Three Metal Carbonyl Complexes Based on Pyridyl Side Chain Functionalized Tetramethylcyclopentadienyl Ligand[J]. Chinese Journal of Structural Chemistry,
2015, 34(6): 931-937.
doi:
10.14102/j.cnki.0254-5861.2011-0639

Syntheses and Crystal Structures of Three Metal Carbonyl Complexes Based on Pyridyl Side Chain Functionalized Tetramethylcyclopentadienyl Ligand
摘要:
Thermal treatment of the pyridyl side chain functionalized tetramethyl cyclopentadiene C5Me4CH2(C5H4N) with Fe(CO)5, Ru3(CO)12 and Mo(CO)6 in refluxing xylene respectively gave the corresponding dinuclear metal carbonyl complexes 1~3. These complexes have been characterized by elemental analysis, IR and 1H NMR spectra. The molecular structures of 1~3 were determined by X-ray diffraction analysis.
English
Syntheses and Crystal Structures of Three Metal Carbonyl Complexes Based on Pyridyl Side Chain Functionalized Tetramethylcyclopentadienyl Ligand
Abstract:
Thermal treatment of the pyridyl side chain functionalized tetramethyl cyclopentadiene C5Me4CH2(C5H4N) with Fe(CO)5, Ru3(CO)12 and Mo(CO)6 in refluxing xylene respectively gave the corresponding dinuclear metal carbonyl complexes 1~3. These complexes have been characterized by elemental analysis, IR and 1H NMR spectra. The molecular structures of 1~3 were determined by X-ray diffraction analysis.
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Key words:
- cyclopentadienyl
- / lmetal carbonyl
- / X-ray diffraction
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