Temperature Dependent Assembly, Structural Diversity and Luminescent Property in Two Novel Cd Coordination Polymers

Citation: WANG Jian, LIN Ping, DU Shao-Wu. Temperature Dependent Assembly, Structural Diversity and Luminescent Property in Two Novel Cd Coordination Polymers[J]. Chinese Journal of Structural Chemistry, 2015, 34(6): 945-952. doi: 10.14102/j.cnki.0254-5861.2011-0605 shu

Temperature Dependent Assembly, Structural Diversity and Luminescent Property in Two Novel Cd Coordination Polymers

1.
a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
2.
b Graduate University of Chinese Academy of Sciences, Beijing 100049, China

通讯作者: LIN Ping,

基金项目:
This work was supported by the National Basic Research Program of China (973 Program, 2012CB821702) (973 Program, 2012CB821702)

摘要: Temperature dependent assembly of two novel Cd coordination polymers with the phen and H₂MIP ligands (phen=1,10-phenanthrolion and H₂MIP=5-methyl-isophthalic acid), formulated as Cd₂(MIP)₂(phen)₂ (1) and Cd₃(MIP)₃(H₂MIP)(phen)₂ (2). They have been structurally characterized by single-crystal X-ray diffraction, elemental analysis, FT-IR spectra and TGA. 1 crystallizes in the monoclinic space group P2/n, while 2 crystallizes in the triclinic space group P1. 1 shows a 2D (two-dimensional) plane and 2 shows a 1D (one-dimensional) chain. In addition, their solid-state luminescent properties have also been investigated.

关键词:

English