Near-infrared and Multicolor Electrochromic Device Based on Polyaniline Derivative

Citation: Zhong-qiu Tong, Hai-ming Lv, Jiu-peng Zhao, Yao Li. Near-infrared and Multicolor Electrochromic Device Based on Polyaniline Derivative[J]. Chinese Journal of Polymer Science, 2014, 32(8): 1040-1051. doi: 10.1007/s10118-014-1483-0 shu

Near-infrared and Multicolor Electrochromic Device Based on Polyaniline Derivative

1.
Center for Composite Materials and Structure, Harbin Institute of Technology, Harbin 150001, China
2.
School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China
基金项目:
This work was financially supported by the National Natural Science Foundation of China (Nos. 51010005, 91216123 and 51174063), Natural Science Funds for Distinguished Young Scholar of Heilongjiang Province and the project of International Cooperation supported by Ministry of Science and Technology of China (2013DFR10630).

摘要: Electroactive conducting copolymers of aniline (ANI) and diphenylamine (DPA) are prepared on indium tin oxide (ITO) surface from 1 mol/L H2SO4 aqueous solution with different feed ratios of ANI to DPA by using a potentiostatic method. FTIR spectra and SEM measurements are used to confirm the formation of copolymers. Due to the combination of the N,N-diphenyl benzidine and aniline units in the molecular chain, the copolymer films exhibit improved electrochemical and electrochromic properties, compared to PANI and PDPA. The copolymer [marked as P(ANI9-co-DPA1)] film prepared at a ratio of 9:1 (ANI/DPA) exhibits novel transmittance modulation both in visible and near-infrared (NIR) region between -0.8 V and 0.8 V (52% and 67% respectively) and fast response time (3.6 s for coloration and 2.3 s for bleaching at 600 nm). An electrochromic device (ECD) based on P(ANI9-co-DPA1) and PEDOT:PSS is also fabricated and shows a multicolor electrochromic performance, with a good optical contrast (29% in visible region and 40% in NIR region), acceptable response time (8.3 s for coloration and 7.5 s for bleaching at 600 nm) and long-term stability. Clear color changes from transparent (-0.8 V), bright green (0 V), seagreen (0.4 V) to dark slate gray (0.8 V) are demonstrated.

关键词:

English

Near-infrared and Multicolor Electrochromic Device Based on Polyaniline Derivative

1.
Center for Composite Materials and Structure, Harbin Institute of Technology, Harbin 150001, China
2.
School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China
Received Date: 22 November 2013
Revised Date: 13 March 2014
Available Online: 05 August 2014
Fund Project:
This work was financially supported by the National Natural Science Foundation of China (Nos. 51010005, 91216123 and 51174063), Natural Science Funds for Distinguished Young Scholar of Heilongjiang Province and the project of International Cooperation supported by Ministry of Science and Technology of China (2013DFR10630).

Abstract: Electroactive conducting copolymers of aniline (ANI) and diphenylamine (DPA) are prepared on indium tin oxide (ITO) surface from 1 mol/L H2SO4 aqueous solution with different feed ratios of ANI to DPA by using a potentiostatic method. FTIR spectra and SEM measurements are used to confirm the formation of copolymers. Due to the combination of the N,N-diphenyl benzidine and aniline units in the molecular chain, the copolymer films exhibit improved electrochemical and electrochromic properties, compared to PANI and PDPA. The copolymer [marked as P(ANI9-co-DPA1)] film prepared at a ratio of 9:1 (ANI/DPA) exhibits novel transmittance modulation both in visible and near-infrared (NIR) region between -0.8 V and 0.8 V (52% and 67% respectively) and fast response time (3.6 s for coloration and 2.3 s for bleaching at 600 nm). An electrochromic device (ECD) based on P(ANI9-co-DPA1) and PEDOT:PSS is also fabricated and shows a multicolor electrochromic performance, with a good optical contrast (29% in visible region and 40% in NIR region), acceptable response time (8.3 s for coloration and 7.5 s for bleaching at 600 nm) and long-term stability. Clear color changes from transparent (-0.8 V), bright green (0 V), seagreen (0.4 V) to dark slate gray (0.8 V) are demonstrated.

Key words:

1. [1]
  Kaya, E., Balan, A., Baran, D., Cirpan, A. and Toppare, L., Org. Electron., 2011, 12: 202
2. [2]
  Hwang, J., Son, J.I. and Shim, Y.B., Sol. Energy Mater. Sol. Cells, 2010, 94: 1286
3. [3]
  Camurlu, P. and Gultekin, C., Sol. Energy Mater. Sol. Cells, 2012, 107: 142
4. [4]
  Madrigal, M.M.P., Giannotti, M.I., Oncins, G., Franco, L., Armelin, E., Puiggali, J., Sanz, F., Del valle, L.J. and Aleman, C., Polym. Chem., 2013, 4: 568
5. [5]
  Garcia, G., Moral, M., Garzon, A., Granadino Roldan, J.M., Navarro, A. and Fernandez Gomez, M., Org. Electron., 2012, 13: 3244
6. [6]
  Kim, Y.G., Walker, J., Samuelson, L.A. and Kumar, J., Nano Lett., 2003, 3: 523
7. [7]
  Bejbouji, H., Vignau, L., Miane, J.L., Dang, M.T., Oualim, E., Harmouchi, M. and Mohammed, A., Sol. Energy Mater. Sol. Cells, 2010, 94: 176
8. [8]
  Crimsdale, A.C., Chan, K.L., Martin, R.E., Jokisz, P.G. and Holmes, A.B., Chem. Rev., 2009, 109: 897
9. [9]
  Beaupre, S., Boudreault, P.T. and Leclerc, M., Adv. Mater., 2010, 22: E6
10. [10]
  Bessire, A., Duhamel, C., Badot, J.C., Lucas, V. and Certiat, M.C., Electrochim. Acta, 2004, 49: 2051
11. [11]
  Wei, J., Xiong, S.X., Bai, Y., Jia, P.T., Ma, J. and Lu, X.H., Sol. Energy Mater. Sol. Cells, 2012, 99: 141
12. [12]
  Montazami, R., Jain, V. and Heflin, J.R., Electrochim. Acta, 2010, 56: 990
13. [13]
  Manisankar, P., Vedhi, C., Selvanathan, G. and Somasundaram, R.M., Chem. Mater., 2005, 17: 1722
14. [14]
  Huang, L.T., Yen, H.J., Wu, J.H. and Liou, G.S., Org. Electron., 2012, 13: 840
15. [15]
  Rajendran, V., Gopalan, A., Vasudevan, T. and Wen, T.C., J. Electrochem. Soc., 2000, 147: 3014
16. [16]
  Guay, J., Paynter, R. and Dao, L.H., Macromolecules, 1990, 23: 3598
17. [17]
  Tsai, Y.T., Wen, T.C. and Gopalan, A., Sens. Actuators, B, 2003, 96: 646
18. [18]
  Wen, T.C., Chen, J.B. and Gopalan, A., Mater. Lett., 2002, 57: 280
19. [19]
  Sasikumar, R. and Manisankar, P., Polymer, 2011, 52: 3710
20. [20]
  Tang, H.Q., Yamashita, T., Kitani, A. and Ito, S., Electrochim. Acta, 1998, 43: 2237
21. [21]
  Chandrasekhar, P., Zay, B.J., Birur, G.C., Rawal, S., Pierson, E.A., Kauder, L. and Swanson, T., Adv. Funct. Mater., 2002, 12: 95
22. [22]
  Bar, G., Larina, N., Grinis, L., Kokshin, V., Gvishi, R., Kiryuschev, I., Zaban, A. and Khodorkovsky, V., Sol. Energy Mater. Sol. Cells, 2012, 99: 123
23. [23]
  Trchov, M., eděnkov, I. and Tobolkov, E., Polym. Degrad. Stab., 2004, 86: 179
24. [24]
  Deepa, M., Ahmad, S., Sood, K.N., Alam, J., Ahmad, S. and Srivastava, A.K., Electrochim. Acta, 2007, 52: 7453
25. [25]
  Ameen, S., Ali, V., Zulfequar, M., Haq, M.M. and Hussain, M., J. Appl. Polym. Sci., 2009, 112: 2315
26. [26]
  Tang, Q.W., Cai, H.Y., Yuan, S.S. and Wang, X., J. Mater. Chem. A, 2013, 1: 317
27. [27]
  Zhang, H.B., Wang, J.X., Wang, Z., Zhang, F.B. and Wang, S.C., Synt. Met., 2009, 159: 277
28. [28]
  Bade, K., Tsakova, V. and Schultze, J. W., Electrochim. Acta, 1992, 37: 2255
29. [29]
  Wu, M.S., Wen, T.C. and Gopalan, A., J. Electrochem. Soc., 2001, 148: D65
30. [30]
  Chung, C.Y., Wen, T.C. and Gopalan, A., Electrochim. Acta, 2001, 47: 423
31. [31]
  Feher, K. and Inzelt, G., Electrochim. Acta, 2002, 47: 3551
32. [32]
  Kang, J.H., Oh, Y.J., Peak, S.M., Hwang, S.J. and Choy, J.H., Sol. Energy Mater. Sol. Cells, 2009, 93: 2040
33. [33]
  Xu, N., Shen, X.D., Cui, S. and Yi, X.B., High Perform. Polym., 2011, 23: 489
34. [34]
  Huang, L.M., Chen, C.H., Wen, T.C. and Gopalan, A., Electrochim. Acta, 2006, 51: 2756
35. [35]
  Lincker, F., Delbosc, N., Baily, S., Bettignies, R.D., Billon, M., Pron, A. and Demadrille, R., Adv. Funct. Mater., 2008, 18: 3444
36. [36]
  Yang, C.H., Yang, T.C., Chen, C.H. and Tsai, M.S., J. Electrochem. Soc., 2006, 153: E85
37. [37]
  Kawahara, J., Ersman, P.A., Engquist, I. and Berggren, M., Org. Electron., 2012, 13: 469
38. [38]
  Tung, T.S. and Ho, K.C., Sol. Energy Mater. Sol. Cells, 2006, 90: 521
39. [39]
  Granqvist, C.G., Sol. Energy Mater. Sol. Cells, 2012, 99: 1
40. [40]
  Deepa, M., Awadhia, A. and Bhandari, S., Phys. Chem. Chem. Phys., 2009, 11: 5674
41. [41]
  Cvjeti?anin, N.D. and Mentus, S., Phys. Chem. Chem. Phys., 1999, 1: 5157

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 970
HTML全文浏览量: 19

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Near-infrared and Multicolor Electrochromic Device Based on Polyaniline Derivative

English

Near-infrared and Multicolor Electrochromic Device Based on Polyaniline Derivative

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Near-infrared and Multicolor Electrochromic Device Based on Polyaniline Derivative

English

Near-infrared and Multicolor Electrochromic Device Based on Polyaniline Derivative

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs