Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

Citation: Jin-long Pan, Zhen Li, Li-fen Zhang, Zhen-ping Cheng, Xiu-lin Zhu. Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent[J]. Chinese Journal of Polymer Science, 2014, 32(8): 1010-1018. doi: 10.1007/s10118-014-1481-2 shu

Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

1.
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
基金项目:
This work was financially supported by the National Natural Science Foundation of China (Nos. 21174096, 21274100 and 21234005), the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20103201110005), the Project of International Cooperation of the Ministry of Science and Technology of China (No. 2011DFA50530), and the project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

摘要: Atom transfer radical polymerization of styrene (St) and methyl methacrylate (MMA) in bulk and in different solvents using activators generated by electron transfer (AGET ATRP) were investigated in the presence of a limited amount of air using FeCl36H2O as the catalyst, ascorbic acid sodium salt (AsAc-Na) as the reducing agent, and a cheap and commercially available tetrabutylammonium bromide (TBABr) as the ligand. It was found that polymerization in THF resulted in shorter induction period than that in bulk and in toluene for AGET ATRP of St, while referring to AGET ATRP of MMA, polymerization in THF showed three advantages compared with that in bulk and toluene: 1) shortening the induction period, 2) enhancing the polymerization rate and 3) having better controllability. The living features of the obtained polymers were verified by chain end analysis and chain-extension experiments.

关键词:

Atom transfer radical polymerization (ATRP)
/ AGET ATRP
/ Iron catalyst
/ Kinetics (polym)

English

Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

1.
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
Received Date: 14 November 2013
Revised Date: 14 December 2013
Available Online: 05 August 2014
Fund Project:
This work was financially supported by the National Natural Science Foundation of China (Nos. 21174096, 21274100 and 21234005), the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20103201110005), the Project of International Cooperation of the Ministry of Science and Technology of China (No. 2011DFA50530), and the project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Abstract: Atom transfer radical polymerization of styrene (St) and methyl methacrylate (MMA) in bulk and in different solvents using activators generated by electron transfer (AGET ATRP) were investigated in the presence of a limited amount of air using FeCl36H2O as the catalyst, ascorbic acid sodium salt (AsAc-Na) as the reducing agent, and a cheap and commercially available tetrabutylammonium bromide (TBABr) as the ligand. It was found that polymerization in THF resulted in shorter induction period than that in bulk and in toluene for AGET ATRP of St, while referring to AGET ATRP of MMA, polymerization in THF showed three advantages compared with that in bulk and toluene: 1) shortening the induction period, 2) enhancing the polymerization rate and 3) having better controllability. The living features of the obtained polymers were verified by chain end analysis and chain-extension experiments.

Key words:

Atom transfer radical polymerization (ATRP)
/ AGET ATRP
/ Iron catalyst
/ Kinetics (polym)

1. [1]
  Kato, M., Kamigaito, M., Sawamoto, M. and Higashimura, T., Macromolecules, 1995, 28: 1721
2. [2]
  Wang, J.S. and Matyjaszewski, K., Macromolecules, 1995, 28: 7901
3. [3]
  Najafi, M., Roghani-Mamaqani, H., Salami-Kalajahi, M. and Haddadi-Asla, V., Chinese J. Polym. Sci., 2010, 28(4): 483
4. [4]
  Bai, L.B., Zheng, R.R., Li, W.L., Wu, Y.G., Ba, X.W. and Wang, H. J., Chinese J. Polym. Sci., 2013, 31(7): 1038
5. [5]
  Zhang, C., Zhu, W., Gao, L. and Chen, Y.M., Chinese J. Polym. Sci., 2011, 29(6): 762
6. [6]
  Liu, W.D., Zhang, Y.H., Fang, L.F., Zhu, B.K. and Zhu, L.P., Chinese J. Polym. Sci., 2012, 30(4): 568
7. [7]
  Tang, Q., Cheng, F., Cui, J. and Chen, Y., Chinese J. Polym. Sci., 2013, 31(7): 1046
8. [8]
  Xing, Y.H., Lin, S.L. and Lin, J.P., Chinese J. Polym. Sci., 2013, 31(5): 833
9. [9]
  Min, K., Gao, H.F. and Matyjaszewski, K., J. Am. Chem. Soc., 2005, 127: 3825
10. [10]
  Jakubowski, W. and Matyjaszewski, K., Macromolecules, 2005, 38: 4139
11. [11]
  Bai, L.J., Zhang, L.F., Cheng, Z.P. and Zhu, X.L., Polym. Chem., 2012, 3: 2685
12. [12]
  Matyjaszewski, K. and Xia, J.H., Chem. Rev., 2001, 101: 2921
13. [13]
  Tsarevsky, N.V. and Matyjaszewski, K., Chem. Rev., 2007, 107: 2270
14. [14]
  Cheng, Z.P., Zhu, X.L., Chen, J.Y. and Lu, J.M., J. Macromol. Sci. Part A: Pure Appl. Chem., 2003, A40: 1157
15. [15]
  Cheng, Z.P., Zhu, X.L., Zhang, L.F., Zhou, N.C. and Xue, X.R., Polym. Bull., 2003, 49: 363
16. [16]
  Ishio, M., Terashima, T., Ouchi, M. and Sawamoto, M., Macromolecules, 2010, 43: 920
17. [17]
  Gibson, V.C., OReilly, R.K., Reed, W., Wass, D.F., White, A.J.P. and Williams, D.J., Chem. Commun., 2002, 1850
18. [18]
  He, D., Xue, Z.G., Khan, M.Y., Noh, S.Y., Lyoo, W.S., J. Polym. Sci., Part A: Polym. Chem., 2010, 48: 144
19. [19]
  Uchiike, C., Terashima, T., Ouchi, M., Ando, T., Kamigaito, M. and Sawamoto, M., Macromolecules, 2007, 40: 8658
20. [20]
  Xue, Z.G., He, D., Noh, S.K. and Lyoo, W.S., Macromolecules, 2009, 42: 2949
21. [21]
  Ishio, M., Katsube, M., Ouchi, M., Sawamoto, M. and Inoue, Y., Macromolecules, 2009, 42: 188
22. [22]
  Zhu, S.M. and Yan, D.Y., Macromolecules, 2000, 33: 8233
23. [23]
  Zhang, L.F., Cheng, Z.P., Tang, F., Li, Q. and Zhu, X.L., Macromol. Chem. Phys., 2008, 209: 1705
24. [24]
  Ando, T., Kato, M., Kamigaito, M. and Sawamoto, M., Macromolecules, 1996, 29: 1070
25. [25]
  Uegaki, H., Kotani, Y., Kamigaito, M. and Sawamoto, M., Macromolecules, 1998, 31: 6756
26. [26]
  Granel, C., Dubois, P., Jerome, R. and Teyssie, P., Macromolecules, 1996, 29: 8576
27. [27]
  Pascual, S., Coutin, B., Tardi, M., Polton, A. and Varion, J.P., Macromolecules, 1999, 32: 1432
28. [28]
  Miao, J., Jiang, H.J., Zhang, L.F., Wu, Z.Q., Cheng, Z.P. and Zhu, X.L., RSC Advances, 2012, 2: 840
29. [29]
  Bolm, C., Legros, J., Paih, J.L. and Zani, L., Chem. Rev., 2004, 104: 6217
30. [30]
  Enthaler, S., Junge, K. and Beller, M., Angew. Chem., Int. Ed., 2008, 47: 3317
31. [31]
  Ando, T., Kamigaito, M. and Sawamoto, M., Macromolecules, 1997, 30: 4507
32. [32]
  Kotani, Y., Kamigaito, M. and Sawamoto, M., Macromolecules, 1999, 32: 6877
33. [33]
  Onishi, I., Baek, K.Y., Kotani, Y., Kamigaito, M. and Sawamoto, M., J. Polym. Sci. Part A: Polym. Chem., 2002, 40: 2033
34. [34]
  Zhang, L.F., Cheng, Z.P., Shi, S.P., Li, Q. and Zhu, X.L., Polymer, 2008, 49: 3054
35. [35]
  Zhu, S.M. and Yan, D.Y., Macromol. Rapid Commun., 2000, 21: 1209
36. [36]
  Chen, H., Liu, J.S. and Wang, C.G., Polym. Int., 2006, 55: 171
37. [37]
  Teodorescu, M., Gaynor, S.G. and Matyjaszewski, K., Macromolecules, 2000, 33: 2335
38. [38]
  Ishio, M., Katsube, M., Ouchi, M., Sawamoto, M. and Inoue, Y., Macromolecules, 2009, 42: 188
39. [39]
  Bai, L.J., Zhang, L.F., Zhang, Z.B., Zhou, N.C., Tu, Y.F., Cheng, Z.P. and Zhu, X.L., Macromolecules, 2010, 43: 9283
40. [40]
  Seelige, F. and Matyjaszewski, K., Macromolecules, 2009, 42: 6050
41. [41]
  Wang, Y. and Matyjaszewski, K., Macromolecules, 2011, 44: 1226
42. [42]
  Luo, R., Chen, Y. and Sen, A., J. Polym. Sci. Part A: Polym. Chem., 2008, 46: 5499
43. [43]
  Chen, Y. and Sen, A., Macromolecules, 2009, 42: 3951
44. [44]
  He, W.J., Zhang, L.F., Bai, L.J., Zhang, Z.B., Zhu, J., Cheng, Z.P. and Zhu, X.L., Macromol. Chem. Phys., 2011, 212: 1474
45. [45]
  Tao, M.X., Zhang, L.F., Jiang, H.J., Zhang, Z.B., Zhu, J., Cheng, Z.P. and Zhu, X.L., Macromol. Chem. Phys., 2011, 212: 1481
46. [46]
  Guo, T., Zhang, L.F., Jiang, H.J., Zhang, Z.B., Zhu, J., Cheng, Z.P. and Zhu, X.L., Polym. Chem., 2011, 2: 2385
47. [47]
  Bai, L.J., Zhang, L.F., Zhang, Z.B., Zhu, J., Zhou, N.C., Cheng, Z.P. and Zhu, X.L., J. Polym. Sci. Part A: Polym. Chem., 2011, 49: 3970
48. [48]
  Bai, L.J., Zhang, L.F., Zhang, Z.B., Zhu, J., Zhou, N.C., Cheng, Z.P. and Zhu, X.L., J. Polym. Sci. Part A: Polym. Chem., 2011, 49: 3980
49. [49]
  Bai, L.J., Zhang, L.F., Zhu, J., Cheng, Z.P. and Zhu, X.L., J. Polym. Sci. Part A: Polym. Chem., 2009, 47: 2002

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 975
HTML全文浏览量: 21

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

English

Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

English

Iron-mediated AGET ATRP of Styrene and Methyl Methacrylate Using Ascorbic Acid Sodium Salt as Reducing Agent

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs