引用本文:
Jin LU, Jun Hua DU, Wei Shan Li, Jia Mo FU. Formation and Oxidation of Hydrogen Molybdenum Bronze on Platinum Electrode in Sulfuric Acid Solution[J]. Chinese Chemical Letters,
2004, 15(6): 703-706.
Citation: Jin LU, Jun Hua DU, Wei Shan Li, Jia Mo FU. Formation and Oxidation of Hydrogen Molybdenum Bronze on Platinum Electrode in Sulfuric Acid Solution[J]. Chinese Chemical Letters, 2004, 15(6): 703-706.

Citation: Jin LU, Jun Hua DU, Wei Shan Li, Jia Mo FU. Formation and Oxidation of Hydrogen Molybdenum Bronze on Platinum Electrode in Sulfuric Acid Solution[J]. Chinese Chemical Letters, 2004, 15(6): 703-706.

Formation and Oxidation of Hydrogen Molybdenum Bronze on Platinum Electrode in Sulfuric Acid Solution
摘要:
Hydrogen molybdenum bronze (HxMoO3) can be electrodeposited on platinum and oxidized in two steps to the hydrogen molybdenum bronze with less amount of hydrogen HyMoO3 (y3 when platinum electrode is cycled from -0.2 to 1.3V (vs. SCE) in 0.05 mol/L Na2MoO4+0.5 mol/L H2SO4 solution. During the formation of HxMoO3, the electrochemical reduction of molybdate existing in the form of polymolydate is reversible and is about a five-electron transfer reaction.
English
Formation and Oxidation of Hydrogen Molybdenum Bronze on Platinum Electrode in Sulfuric Acid Solution
Abstract:
Hydrogen molybdenum bronze (HxMoO3) can be electrodeposited on platinum and oxidized in two steps to the hydrogen molybdenum bronze with less amount of hydrogen HyMoO3 (y3 when platinum electrode is cycled from -0.2 to 1.3V (vs. SCE) in 0.05 mol/L Na2MoO4+0.5 mol/L H2SO4 solution. During the formation of HxMoO3, the electrochemical reduction of molybdate existing in the form of polymolydate is reversible and is about a five-electron transfer reaction.
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Key words:
- Hydrogen molybdenum bronze
- / formation and oxidation
- / platinum
- / sulfuric acid solution

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