引用本文:
Hong Hui ZHUANG, Ding Ming WU, Jian Quan HUANG, Jin Ling HUANG. SYNTHESIS AND STRUCTURE OF TETRANUCLEAR MOLYBDENUM CLUSTER COMPOUND[Mo4S4(μ-O2CC6H5)2(dtp)4][J]. Chinese Chemical Letters,
1991, 2(7): 553-554.
Citation: Hong Hui ZHUANG, Ding Ming WU, Jian Quan HUANG, Jin Ling HUANG. SYNTHESIS AND STRUCTURE OF TETRANUCLEAR MOLYBDENUM CLUSTER COMPOUND[Mo4S4(μ-O2CC6H5)2(dtp)4][J]. Chinese Chemical Letters, 1991, 2(7): 553-554.
Citation: Hong Hui ZHUANG, Ding Ming WU, Jian Quan HUANG, Jin Ling HUANG. SYNTHESIS AND STRUCTURE OF TETRANUCLEAR MOLYBDENUM CLUSTER COMPOUND[Mo4S4(μ-O2CC6H5)2(dtp)4][J]. Chinese Chemical Letters, 1991, 2(7): 553-554.
SYNTHESIS AND STRUCTURE OF TETRANUCLEAR MOLYBDENUM CLUSTER COMPOUND[Mo4S4(μ-O2CC6H5)2(dtp)4]
摘要:
The cluster compound [Mo4S4(μ-O2CC5H5)2(dtp)4](dtp=S2P(OEt)2)was obtained by the ligand substitution reaction of tetranuclear molybdenum cluster [Mo4S4(μ-dtp)2(dtp)4]in the mixed solvent of acetone, ethanol and water in the presence of C6H5CO2Na.It is monoclinic and crystallizes in space group C2/c, Mr=1495.09, a=12.175(5), b=22.01(1), c=20.875(9)Å, β=99.04(4)°V=5575(5)Å3;Z=4;Dc=1.78g/cm3.Final R factor is 0.066.The result reveals that the[Mo4S4] cluster core and t-(dtp)-1 ligands are retained and only μ-bridged(dtp)-1ligands are substituted by(C6H5CO2)-1 in the substitution reaction, thus producing the new title cluster compound, the structure of which contains two species of bidentate ligand.
English
SYNTHESIS AND STRUCTURE OF TETRANUCLEAR MOLYBDENUM CLUSTER COMPOUND[Mo4S4(μ-O2CC6H5)2(dtp)4]
Abstract:
The cluster compound [Mo4S4(μ-O2CC5H5)2(dtp)4](dtp=S2P(OEt)2)was obtained by the ligand substitution reaction of tetranuclear molybdenum cluster [Mo4S4(μ-dtp)2(dtp)4]in the mixed solvent of acetone, ethanol and water in the presence of C6H5CO2Na.It is monoclinic and crystallizes in space group C2/c, Mr=1495.09, a=12.175(5), b=22.01(1), c=20.875(9)Å, β=99.04(4)°V=5575(5)Å3;Z=4;Dc=1.78g/cm3.Final R factor is 0.066.The result reveals that the[Mo4S4] cluster core and t-(dtp)-1 ligands are retained and only μ-bridged(dtp)-1ligands are substituted by(C6H5CO2)-1 in the substitution reaction, thus producing the new title cluster compound, the structure of which contains two species of bidentate ligand.
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