Citation:
Deepa Puthanparambil a, b, Casey Kimball a, b, Shaw Ling Hsu a, b, Zhiyong Ren c. STRUCTURAL EVOLUTION IN BIORENEWABLE SOY BASED POLYURETHANES[J]. Chinese Journal of Polymer Science,
2009, 27(4): 447-454.
STRUCTURAL EVOLUTION IN BIORENEWABLE SOY BASED POLYURETHANES
摘要:
Spectroscopic studies have revealed that the amount of polyureas formed and the kinetics of their formation in soy based polyurethane systems are considerably different from traditional systems employing ethylene oxide-propylene oxide (EO-PO) based polyols. The aggregation of polyureas was characterized by the hydrogen bonds formed utilizing FTIR spectroscopy. This study offered the opportunity to assign the previously undefined infrared features. The structural transformation is reflected in the segmental relaxation kinetics characterized by spin-spin diffusion most conveniently measured using low field NMR. The reaction kinetics and the products formed are directly related to the hydrophobic nature of the soy based polyols and its inability to disperse water.
English
STRUCTURAL EVOLUTION IN BIORENEWABLE SOY BASED POLYURETHANES
Abstract:
Spectroscopic studies have revealed that the amount of polyureas formed and the kinetics of their formation in soy based polyurethane systems are considerably different from traditional systems employing ethylene oxide-propylene oxide (EO-PO) based polyols. The aggregation of polyureas was characterized by the hydrogen bonds formed utilizing FTIR spectroscopy. This study offered the opportunity to assign the previously undefined infrared features. The structural transformation is reflected in the segmental relaxation kinetics characterized by spin-spin diffusion most conveniently measured using low field NMR. The reaction kinetics and the products formed are directly related to the hydrophobic nature of the soy based polyols and its inability to disperse water.
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