{"综合评述":[{"abstractInfo":"综述了贵金属纳米粒子修饰的核胶球材料的研究进展。由于贵金属壳-胶球核复合材料具有高的稳定性和优异的光学、催化等性质,是当前材料科学研究领域的一个热点。因此,发展简单的、大量的制备这种复合材料的方法,以及广泛深入地研究其性能和应用具有十分重要的意义。","abstractInfoCn":"综述了贵金属纳米粒子修饰的核胶球材料的研究进展。由于贵金属壳-胶球核复合材料具有高的稳定性和优异的光学、催化等性质,是当前材料科学研究领域的一个热点。因此,发展简单的、大量的制备这种复合材料的方法,以及广泛深入地研究其性能和应用具有十分重要的意义。","abstractInfoEn":"The recent progress in the area of core colloids modified with noble metal nanoparticles is reviewed.The researches on these composite materials are hot topic in the area of material science due to their high stability,excellently catalytic and optical properties.Hence,developing simple strategy with high throughput for the preparation of these composites is very important for their further application.","articleNo":"20100401","authorCnList":["周晓光","  田春贵","  王霆","  廖丽霞"],"authorEnList":["ZHOU Xiao-Guanga","  TIAN Chun-Guib","  WANG Tinga","  LIAO Li-Xi"],"authorList":["周晓光","  田春贵","  王霆","  廖丽霞"],"authors":"周晓光,  田春贵,  王霆,  廖丽霞","authorsCn":"周晓光,  田春贵,  王霆,  廖丽霞","authorsEn":"ZHOU Xiao-Guanga,  TIAN Chun-Guib,  WANG Tinga,  LIAO Li-Xi","categoryName":"综合评述","categoryNameCn":"综合评述","categoryNameEn":"","citation":"周晓光,  田春贵,  王霆,  廖丽霞. 贵金属纳米粒子修饰的核胶球复合材料的研究进展. 应用化学, 2010, 27(4): 373-379. doi: 10.3724/SP.J.1095.2010.90676.","citationCn":"周晓光,  田春贵,  王霆,  廖丽霞. 贵金属纳米粒子修饰的核胶球复合材料的研究进展. 应用化学, 2010, 27(4): 373-379. doi: 10.3724/SP.J.1095.2010.90676.","citationEn":"周晓光,  田春贵,  王霆,  廖丽霞. Research Progress on Core Colloids Modified with Noble Metal Nanoparticles. Chinese Journal of Applied Chemistry, 2010, 27(4): 373-379. doi: 10.3724/SP.J.1095.2010.90676.","doi":"10.3724/SP.J.1095.2010.90676","figContent":"","figList":[],"firstFig":"","fpage":"373","highCitedState":"","htmlCount":8,"htmlFile":"","id":"7854558b-5c3e-4dfd-8f00-671d10b05d83","issnPpub":"1000-0518","issue":"4","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"贵金属纳米粒子, 核胶球, 核壳结构复合材料","keywordCn":"贵金属纳米粒子, 核胶球, 核壳结构复合材料","keywordCnList":["贵金属纳米粒子"," 核胶球"," 核壳结构复合材料"],"keywordEn":"noble metal nanoparticle, core colloid, core-shell composite","keywordEnList":["noble metal nanoparticle"," core colloid"," core-shell composite"],"keywordList":["贵金属纳米粒子"," 核胶球"," 核壳结构复合材料"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"379","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":906.85,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"贵金属纳米粒子修饰的核胶球复合材料的研究进展","titleCn":"贵金属纳米粒子修饰的核胶球复合材料的研究进展","titleEn":"Research Progress on Core Colloids Modified with Noble Metal Nanoparticles","viewCount":235,"volume":"27","year":2010}],"研究论文":[{"abstractInfo":"采用同步辐射小角X射线散射(SAXS)技术观察了2个不同乳胶体系的微观结构以及将其混合对结晶行为的影响。结果表明,体积分数为50%的苯乙烯-丙烯酸丁酯共聚物乳胶液在室温下没有结晶。通过对散射强度曲线的拟合,乳胶粒子的平均半径是76nm,小于动态光散射的测量值(80nm)。但50%的苯乙烯-丁二烯共聚物乳胶液发生了结晶。利用面心立方(<i>fcc<\/i>)结构和晶格常数为212nm的晶格衍射进行拟合,发现散射曲线中的所有Bragg衍射峰均对应1个或多个晶面指数。将2种乳胶液混合后各个衍射峰仍能分辨出来,这说明原始乳液中的部分微晶在混合过程中仍然稳定存在。","abstractInfoCn":"采用同步辐射小角X射线散射(SAXS)技术观察了2个不同乳胶体系的微观结构以及将其混合对结晶行为的影响。结果表明,体积分数为50%的苯乙烯-丙烯酸丁酯共聚物乳胶液在室温下没有结晶。通过对散射强度曲线的拟合,乳胶粒子的平均半径是76nm,小于动态光散射的测量值(80nm)。但50%的苯乙烯-丁二烯共聚物乳胶液发生了结晶。利用面心立方(<i>fcc<\/i>)结构和晶格常数为212nm的晶格衍射进行拟合,发现散射曲线中的所有Bragg衍射峰均对应1个或多个晶面指数。将2种乳胶液混合后各个衍射峰仍能分辨出来,这说明原始乳液中的部分微晶在混合过程中仍然稳定存在。","abstractInfoEn":"The microstructures of two samples of latex dispersion system and the influence of their blending on the crystallization behavior were investigated by means of synchrotron small-angle X-ray scattering(SAXS) technique.The experimental results confirmed that the latex dispersion at a volume fraction of 50% composed of styrene-butylacrylate copolymer did not show up crystalline structures at room temperature.By virtue of fitting the scattering intensity distribution curve,the average radius of the latex particle was 76 nm,which is smaller than the value determined by dynamic light scattering(80 nm).However,the crystalline structure can be probed in the latex dispersion of styrene-butadiene copolymer with a solid content of 50%.Each Bragg peak in the scattering profile can be assigned to one or several crystal indices by assuming diffraction from a face-centered-cubic crystalline structure with a lattice constant of 212 nm.The diffraction peaks can be detected after mixing the two latex dispersion samples,implying that the partial crystallites in the original latex solution are still stable in the blending process.","articleNo":"20100402","authorCnList":["姜志勇","  胡珊珊","  门永锋"],"authorEnList":["JIANG Zhi-Yonga","  HU Shan-Shana","  MEN Yong-Feng"],"authorList":["姜志勇","  胡珊珊","  门永锋"],"authors":"姜志勇,  胡珊珊,  门永锋","authorsCn":"姜志勇,  胡珊珊,  门永锋","authorsEn":"JIANG Zhi-Yonga,  HU Shan-Shana,  MEN Yong-Feng","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"姜志勇,  胡珊珊,  门永锋. 小角X射线散射研究乳胶分散液的微观结构. 应用化学, 2010, 27(4): 380-383. doi: 10.3724/SP.J.1095.2010.90360.","citationCn":"姜志勇,  胡珊珊,  门永锋. 小角X射线散射研究乳胶分散液的微观结构. 应用化学, 2010, 27(4): 380-383. doi: 10.3724/SP.J.1095.2010.90360.","citationEn":"姜志勇,  胡珊珊,  门永锋. Microstructure of Latex Dispersion by Small-Angle X-ray Scattering. Chinese Journal of Applied Chemistry, 2010, 27(4): 380-383. doi: 10.3724/SP.J.1095.2010.90360.","doi":"10.3724/SP.J.1095.2010.90360","figContent":"","figList":[],"firstFig":"","fpage":"380","highCitedState":"","htmlCount":20,"htmlFile":"","id":"d219361f-310d-4da3-812e-3c1a2b0e9a9e","issnPpub":"1000-0518","issue":"4","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"SAXS, 乳胶, 微观结构","keywordCn":"SAXS, 乳胶, 微观结构","keywordCnList":["SAXS"," 乳胶"," 微观结构"],"keywordEn":"SAXS, latex dispersion, microstructure","keywordEnList":["SAXS"," latex dispersion"," microstructure"],"keywordList":["SAXS"," 乳胶"," 微观结构"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"383","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":305.99,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"小角X射线散射研究乳胶分散液的微观结构","titleCn":"小角X射线散射研究乳胶分散液的微观结构","titleEn":"Microstructure of Latex Dispersion by Small-Angle X-ray Scattering","viewCount":270,"volume":"27","year":2010},{"abstractInfo":"以二茂铁甲酸(FCA)为模板,选用不同的功能单体制备了一系列分子印迹聚合物,用平衡结合实验考察了它们对模板分子的结合性能。结果表明,以甲基丙烯酸为功能单体制得的印迹聚合物P<sub>1<\/sub>对模板分子有很好的选择性,特异性吸附量△<i>C<\/i><sub>P<\/sub>为23.18μmol/g,�ndState":"","releaseState":"1","secCount":0,"title":"小角X射线散射研究乳胶分散液的微观结构","titleCn":"小角X射线散射研究乳胶分散液的微观结构","titleEn":"Microstructure of Latex Dispersion by Small-Angle X-ray Scattering","viewCount":270,"volume":"27","year":2010},{"abstractInfo":"以二茂铁甲酸(FCA)为模板,选用不同的功能单体制备了一系列分子印迹聚合物,用平衡结合实验考察了它们对模板分子的结合性能。结果表明,以甲基丙烯酸为功能单体制得的印迹聚合物P<sub>1<\/sub>对模板分子有很好的选择性,特异性吸附量△<i>C<\/i><sub>P<\/sub>为23.18μmol/g,印迹因子IF为2.33,竞争性结合实验结果表明,P<sub>1<\/sub>可以将模板分子从结构类似物中分离出来。Scatchard方程研究表明,在研究的浓度范围内聚合物中形成了一类等价的结合位点,其对模板分子的平衡离解常数<i>K<\/i>=1.94mmol/L,最大表观结合量<i>C<\/i><sub>pmax<\/sub>=92.33μmol/g。研究还表明,FCA的羧基是在聚合物的孔穴中产生识别位点的功能基,模板分子上的羧基与MAA的羧基形成双重氢键作用是分子识别的主要作用力。","abstractInfoCn":"以二茂铁甲酸(FCA)为模板,选用不同的功能单体制备了一系列分子印迹聚合物,用平衡结合实验考察了它们对模板分子的结合性能。结果表明,以甲基丙烯酸为功能单体制得的印迹聚合物P<sub>1<\/sub>对模板分子有很好的选择性,特异性吸附量△<i>C<\/i><sub>P<\/sub>为23.18μmol/g,印迹因子IF为2.33,竞争性结合实验结果表明,P<sub>1<\/sub>可以将模板分子从结构类似物中分离出来。Scatchard方程研究表明,在研究的浓度范围内聚合物中形成了一类等价的结合位点,其对模板分子的平衡离解常数<i>K<\/i>=1.94mmol/L,最大表观结合量<i>C<\/i><sub>pmax<\/sub>=92.33μmol/g。研究还表明,FCA的羧基是在聚合物的孔穴中产生识别位点的功能基,模板分子上的羧基与MAA的羧基形成双重氢键作用是分子识别的主要作用力。","abstractInfoEn":"A series of ferrocenecarboxylic acid imprinted polymers from different functional monomers were prepared and their adsorption properties for the template were evaluated by equilibrium binding experiments.The results indicate that the imprinted polymer P<sub>1<\/sub>,prepared with methacrylic acid as the functional monomer, exhibited a higher selectivity for ferrocenecarboxylic acid.The specific binding capacity(△<i>C<\/i><sub>P<\/sub>) and imprinting factor(IF) of P<sub>1<\/sub> are 23.18 μmol/g and 2.33,respectively.The results of competitive binding experiments show that P<sub>1<\/sub> can separate the template from its structural analogues.Scatchard analysis demonstrates that one equal class of binding sites was formed in the imprinted polymer in the studied concentration range.The dissociation constant and the apparent maximum number of the binding sites are 1.94 mmol/L and 92.33 μmol/g,respectively.The study suggests that the carboxyl of the template is the function group responsible for the formation of complementary interacting site in the polymer P<sub>1<\/sub>,and the double hydrogen bonds formed between the carboxyl groups of ferrocenecarboxylic acid and methacrylic acid are the main interactions in the recognition process.","articleNo":"20100403","authorCnList":["许志锋","  吴双","  吴小辉","  邝代治","  张复兴","  王剑秋"],"authorEnList":["XU Zhi-Feng","  WU Shuang","  WU Xiao-Hui","  KUANG Dai-Zhi","  ZHANG Fu-Xing","  WANG Jian-Qiu"],"authorList":["许志锋","  吴双","  吴小辉","  邝代治","  张复兴","  王剑秋"],"authors":"许志锋,  吴双,  吴小辉,  邝代治,  张复兴,  王剑秋","authorsCn":"许志锋,  吴双,  吴小辉,  邝代治,  张复兴,  王剑秋","authorsEn":"XU Zhi-Feng,  WU Shuang,  WU Xiao-Hui,  KUANG Dai-Zhi,  ZHANG Fu-Xing,  WANG Jian-Qiu","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"许志锋,  吴双,  吴小辉,  邝代治,  张复兴,  王剑秋. 二茂铁甲酸分子印迹聚合物的制备、识别机理和结合特性. 应用化学, 2010, 27(4): 384-389. doi: 10.3724/SP.J.1095.2010.90385.","citationCn":"许志锋,  吴双,  吴小辉,  邝代治,  张复兴,  王剑秋. 二茂铁甲酸分子印迹聚合物的制备、识别机理和结合特性. 应用化学, 2010, 27(4): 384-389. doi: 10.3724/SP.J.1095.2010.90385.","citationEn":"许志锋,  吴双,  吴小辉,  邝代治,  张复兴,  王剑秋. Preparation,Mechanism of Recognition and Binding Characteristics of Ferrocenecarboxylic Acid Imprinted Polymers. Chinese Journal of Applied Chemistry, 2010, 27(4): 384-389. doi: 10.3724/SP.J.1095.2010.90385.","doi":"10.3724/SP.J.1095.2010.90385","figContent":"","figList":[],"firstFig":"","fpage":"384","highCitedState":"","htmlCount":23,"htmlFile":"","id":"12a33c80-064f-447a-be21-ff20758ba2ff","issnPpub":"1000-0518","issue":"4","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"分子印迹, 二茂铁甲酸, 甲基丙烯酸, 分子识别","keywordCn":"分子印迹, 二茂铁甲酸, 甲基丙烯酸, 分子识别","keywordCnList":["分子印迹"," 二茂铁甲酸"," 甲基丙烯酸"," 分子识别"],"keywordEn":"molecular imprinting, ferrocenecarboxylic acid, methacrylic acid, molecular recognition","keywordEnList":["molecular imprinting"," ferrocenecarboxylic acid"," methacrylic acid"," molecular recognition"],"keywordList":["分子印迹"," 二茂铁甲酸"," 甲基丙烯酸"," 分子识别"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"389","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":396.47,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"二茂铁甲酸分子印迹聚合物的制备、识别机理和结合特性","titleCn":"二茂铁甲酸分子印迹聚合物的制备、识别机理和结合特性","titleEn":"Preparation,Mechanism of Recognition and Binding Characteristics of Ferrocenecarboxylic Acid Imprinted Polymers","viewCount":331,"volume":"27","year":2010},{"abstractInfo":"与传统的酰氯化试剂相比,固体光气(BTC)是一种性能较好的酰氯化试剂,将其用于各种芳香酸和脂肪酸酰氯化反应,均取得较高的转化率(99%);此外,稀土Lewis酸Yb(OTf)<sub>3<\/sub>对固体光气与有机酸的酰氯化反应有一定催化作用。","abstractInfoCn":"与传统的酰氯化试剂相比,固体光气(BTC)是一种性能较好的酰氯化试剂,将其用于各种芳香酸和脂肪酸酰氯化反应,均取得较高的转化率(99%);此外,稀土Lewis酸Yb(OTf)<sub>3<\/sub>对固体光气与有机酸的酰氯化反应有一定催化作用。","abstractInfoEn":"Compared to traditional acylchloride reagent,bistrichloromethylcarbonate(BTC) is an excellent acylchloride reagent.Aromatic acids and aliphatic acids react with it to afford the corresponding acylchloride compounds in high yields(99%). In addition,Yb(OTf)<sub>3<\/sub> catalyzed efficiently the desired process.","articleNo":"20100404","authorCnList":["王峰","  杨柳波","  王利民","  田禾","  王桂峰"],"authorEnList":["WANG Feng","  YANG Liu-Bo","  WANG Li-Min","  TIAN He","  WANG Gui-Feng"],"authorList":["王峰","  杨柳波","  王利民","  田禾","  王桂峰"],"authors":"王峰,  杨柳波,  王利民,  田禾,  王桂峰","authorsCn":"王峰,  杨柳波,  王利民,  田禾,  王桂峰","authorsEn":"WANG Feng,  YANG Liu-Bo,  WANG Li-Min,  TIAN He,  WANG Gui-Feng","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"王峰,  杨柳波,  王利民,  田禾,  王桂峰. Yb(OTf)<sub>3<\/sub>催化固体光气对有机酸的酰氯化反应. 应用化学, 2010, 27(4): 390-393. doi: 10.3724/SP.J.1095.2010.90406.","citationCn":"王峰,  杨柳波,  王利民,  田禾,  王桂峰. Yb(OTf)<sub>3<\/sub>催化固体光气对有机酸的酰氯化反应. 应用化学, 2010, 27(4): 390-393. doi: 10.3724/SP.J.1095.2010.90 bonds formed between the carboxyl groups of ferrocenecarboxylic acid and methacrylic acid are the main interactions in the recognition process.","articleNo":"20100403","authorCnList":["许志锋","  吴双","  吴小辉","  邝代治","  张复兴","  王剑秋"],"authorEnList":["XU Zhi-Feng","  WU Shuang","  WU Xiao-Hui","  KUANG Dai-Zhi","  ZHANG Fu-Xing","  WANG Jian-Qiu"],"authorList":["许志锋","  吴双","  吴小辉","  邝代治","  张复兴","  王剑秋"],"authors":"许志锋,  吴双,  吴小辉,  邝代治,  张复兴,  王剑秋","authorsCn":"许志锋,  吴双,  吴小辉,  邝代治,  张复兴,  王剑秋","authorsEn":"XU Zhi-Feng,  WU Shuang,  WU Xiao-Hui,  KUANG Dai-Zhi,  ZHANG Fu-Xing,  WANG Jian-Qiu","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"许志锋,  吴双,  吴小辉,  邝代治,  张复兴,  王剑秋. 二茂铁甲酸分子印迹聚合物的制备、识别机理和结合特性. 应用化学, 2010, 27(4): 384-389. doi: 10.3724/SP.J.1095.2010.90385.","citationCn":"许志锋,  吴双,  吴小辉,  邝代治,  张复兴,  王剑秋. 二茂铁甲酸分子印迹聚合物的制备、识别机理和结合特性. 应用化学, 2010, 27(4): 384-389. doi: 10.3724/SP.J.1095.2010.90385.","citationEn":"许志锋,  吴双,  吴小辉,  邝代治,  张复兴,  王剑秋. Preparation,Mechanism of Recognition and Binding Characteristics of Ferrocenecarboxylic Acid Imprinted Polymers. Chinese Journal of Applied Chemistry, 2010, 27(4): 384-389. doi: 10.3724/SP.J.1095.2010.90385.","doi":"10.3724/SP.J.1095.2010.90385","figContent":"","figList":[],"firstFig":"","fpage":"384","highCitedState":"","htmlCount":23,"htmlFile":"","id":"12a33c80-064f-447a-be21-ff20758ba2ff","issnPpub":"1000-0518","issue":"4","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"分子印迹, 二茂铁甲酸, 甲基丙烯酸, 分子识别","keywordCn":"分子印迹, 二茂铁甲酸, 甲基丙烯酸, 分子识别","keywordCnList":["分子印迹"," 二茂铁甲酸"," 甲基丙烯酸"," 分子识别"],"keywordEn":"molecular imprinting, ferrocenecarboxylic acid, methacrylic acid, molecular recognition","keywordEnList":["molecular imprinting"," ferrocenecarboxylic acid"," methacrylic acid"," molecular recognition"],"keywordList":["分子印迹"," 二茂铁甲酸"," 甲基丙烯酸"," 分子识别"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"389","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":396.47,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"二茂铁甲酸分子印迹聚合物的制备、识别机理和结合特性","titleCn":"二茂铁甲酸分子印迹聚合物的制备、识别机理和结合特性","titleEn":"Preparation,Mechanism of Recognition and Binding Characteristics of Ferrocenecarboxylic Acid Imprinted Polymers","viewCount":331,"volume":"27","year":2010},{"abstractInfo":"与传统的酰氯化试剂相比,固体光气(BTC)是一种性能较好的酰氯化试剂,将其用于各种芳香酸和脂肪酸酰氯化反应,均取得较高的转化率(99%);此外,稀土Lewis酸Yb(OTf)<sub>3<\/sub>对固体光气与有机酸的酰氯化反应有一定催化作用。","abstractInfoCn":"与传统的酰氯化试剂相比,固体光气(BTC)是一种性能较好的酰氯化试剂,将其用于各种芳香酸和脂肪酸酰氯化反应,均取得较高的转化率(99%);此外,稀土Lewis酸Yb(OTf)<sub>3<\/sub>对固体光气与有机酸的酰氯化反应有一定催化作用。","abstractInfoEn":"Compared to traditional acylchloride reagent,bistrichloromethylcarbonate(BTC) is an excellent acylchloride reagent.Aromatic acids and aliphatic acids react with it to afford the corresponding acylchloride compounds in high yields(99%). In addition,Yb(OTf)<sub>3<\/sub> catalyzed efficiently the desired process.","articleNo":"20100404","authorCnList":["王峰","  杨柳波","  王利民","  田禾","  王桂峰"],"authorEnList":["WANG Feng","  YANG Liu-Bo","  WANG Li-Min","  TIAN He","  WANG Gui-Feng"],"authorList":["王峰","  杨柳波","  王利民","  田禾","  王桂峰"],"authors":"王峰,  杨柳波,  王利民,  田禾,  王桂峰","authorsCn":"王峰,  杨柳波,  王利民,  田禾,  王桂峰","authorsEn":"WANG Feng,  YANG Liu-Bo,  WANG Li-Min,  TIAN He,  WANG Gui-Feng","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"王峰,  杨柳波,  王利民,  田禾,  王桂峰. Yb(OTf)<sub>3<\/sub>催化固体光气对有机酸的酰氯化反应. 应用化学, 2010, 27(4): 390-393. doi: 10.3724/SP.J.1095.2010.90406.","citationCn":"王峰,  杨柳波,  王利民,  田禾,  王桂峰. Yb(OTf)<sub>3<\/sub>催化固体光气对有机酸的酰氯化反应. 应用化学, 2010, 27(4): 390-393. doi: 10.3724/SP.J.1095.2010.90406.","citationEn":"王峰,  杨柳波,  王利民,  田禾,  王桂峰. Acylchloride Reaction of Organic Acids with Bistrichloromethylcarbonate Catalyzed by Yb(OTf)<sub>3<\/sub>. Chinese Journal of Applied Chemistry, 2010, 27(4): 390-393. doi: 10.3724/SP.J.1095.2010.90406.","doi":"10.3724/SP.J.1095.2010.90406","figContent":"","figList":[],"firstFig":"","fpage":"390","highCitedState":"","htmlCount":53,"htmlFile":"","id":"1055aa14-d0dc-46eb-a765-b385b12abbc3","issnPpub":"1000-0518","issue":"4","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"固体光气, Yb(OTf)<sub>3<\/sub>, 酰氯化, Lewis acid","keywordCn":"固体光气, Yb(OTf)<sub>3<\/sub>, 酰氯化, Lewis acid","keywordCnList":["固体光气"," Yb(OTf)<sub>3<\/sub>"," 酰氯化"," Lewis acid"],"keywordEn":"bistrichloromethylcarbonate(BTC), Yb(OTf)<sub>3<\/sub>, acylchloride reaction, lewis acid","keywordEnList":["bistrichloromethylcarbonate(BTC)"," Yb(OTf)<sub>3<\/sub>"," acylchloride reaction"," lewis acid"],"keywordList":["固体光气"," Yb(OTf)<sub>3<\/sub>"," 酰氯化"," Lewis acid"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"393","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":1,"pdfSize":275.09,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"Yb(OTf)<sub>3<\/sub>催化固体光气对有机酸的酰氯化反应","titleCn":"Yb(OTf)<sub>3<\/sub>催化固体光气对有机酸的酰氯化反应","titleEn":"Acylchloride Reaction of Organic Acids with Bistrichloromethylcarbonate Catalyzed by Yb(OTf)<sub>3<\/sub>","viewCount":345,"volume":"27","year":2010},{"abstractInfo":"通过人工发酵培养,从南海红树林内源真菌<i>Fusariumsp<\/i>.ZZF60的培养液中分离得到:1种新蒽醌衍生物,6,8-二甲氧基-1-甲基-2-(3-氧丁基)蒽醌(<b>1<\/b>),以及5种已知化合物:7-羟基-3-(4-甲氧基苯基)苯并-<i>γ<\/i>-吡喃酮(<b>2<\/b>),2,4-二羟基-6-[(1'<i>E<\/i>,3'<i>E<\/i>)-1',3'-戊二烯基]苯甲醛(<b>3<\/b>),(<i>E<\/i>)-4-羟基肉桂酸甲酯(<b>4<\/b>),4-(4-羟基苯基)-2-丁醇(<b>5<\/b>),4-羟基苯甲酸(<b>6<\/b>)。它们的结构通过MS、NMR等波谱分析推导确定。初步药理活性显示,化合物1抑制体外培养人喉癌细胞Hep2和人肝癌细胞HepG2的IC<sub>50<\/sub>分别为16和23μmol/L。","abstractInfoCn":"通过人工发酵培养,从南海红树林内源真菌<i>Fusarium sp<\/i>.ZZF60的培养液中分离得到:1种新蒽醌衍生物,6,8-二甲氧基-1-甲基-2-(3-氧丁基)蒽醌(<b>1<\/b>),以及5种已知化合物:7-羟基-3-(4-甲氧基苯基)苯并-<i>γ<\/i>-吡喃酮(<b>2<\/b>),2,4-二羟基-6-[(1'<i>E<\/i>,3'<i>E<\/i>)-1',3'-戊二烯基]苯甲醛(<b>3<\/b>),(<i>E<\/i>)-4-羟基肉桂酸甲酯(<b>4<\/b>),4-(4-羟基苯基)-2-丁醇(<b>5<\/b>),4-羟基苯甲酸(<b>6<\/b>)。它们的结构通过MS、NMR等波谱分析推导确定。初步药理活性显示,化合物1抑制体外培养人喉癌细胞Hep2和人肝癌细胞HepG2的IC<sub>50<\/sub>分别为16和23μmol/L。","abstractInfoEn":"A new anthraquinone derivative,6,8-dimethoxy-1-methyl-2-(3-oxobutyl) anthrakunthone(<b>1<\/b>),together with five known compounds,7-hydroxy-3-(4-methoxyphenyl)-chromen-4-one(<b>2<\/b>),2,4-dihydroxy-6-[(1'<i>E<\/i>,3'<i>E<\/i>)-penta-1',3'-dienyl]-benzaldehyde(<b>3<\/b>),(<i>E<\/i>)-4hydroxycinnamic acid methyl ester(<b>4<\/b>),4-(4-hydroxyphenyl)-butan2-ol(<b>5<\/b>),and 4-hydroxybenzoic acid(<b>6<\/b>),were isolated from the marine mangrove endophytic fungus <i>Fusarium sp<\/i>.ZZF60 from the South China Sea.Their structures were elucidated by spectral data of IR,MS and NMR.In the preliminary bioassay,compound <b>1<\/b> showed cytotoxicity towards Hep2 and HepG2 with IC<sub>50<\/sub> values of 16 μmol/L and 23 μmol/L,respectively.","articleNo":"20100405","authorCnList":["黄忠京","  杨瑞云","  郭志勇","  佘志刚","  林永成"],"authorEnList":["HUANG Zhong-Jinga","  YANG Run-Yunb","  GUO Zhi-Yongb","  SHE Zhi-Gangb","  LIN Yong-Cheng"],"authorList":["黄忠京","  杨瑞云","  郭志勇","  佘志刚","  林永成"],"authors":"黄忠京,  杨瑞云,  郭志勇,  佘志刚,  林永成","authorsCn":"黄忠京,  杨瑞云,  郭志勇,  佘志刚,  林永成","authorsEn":"HUANG Zhong-Jinga,  YANG Run-Yunb,  GUO Zhi-Yongb,  SHE Zhi-Gangb,  LIN Yong-Cheng","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"黄忠京,  杨瑞云,  郭志勇,  佘志刚,  林永成. 培养南海红树林内源真菌<i>Fusarium sp<\/i>. ZZF60产新型蒽醌衍生物. 应用化学, 2010, 27(4): 394-397. doi: 10.3724/SP.J.1095.2010.90377.","citationCn":"黄忠京,  杨瑞云,  郭志勇,  佘志刚,  林永成. 培养南海红树林内源真菌<i>Fusarium sp<\/i>. ZZF60产新型蒽醌衍生物. 应用化学, 2010, 27(4): 394-397. doi: 10.3724/SP.J.1095.2010.90377.","citationEn":"黄忠京,  杨瑞云,  郭志勇,  佘志刚,  林永成. New Anthraquinone Derivative Produced by Cultivation of Mangrove Endophytic Fungus <i>Fusarium sp<\/i>. ZZF60 from the South China Sea. Chinese Journal of Applied Chemistry, 2010, 27(4): 394-397. doi: 10.3724/SP.J.1095.2010.90377.","doi":"10.3724/SP.J.1095.2010.90377","figContent":"","figList":[],"firstFig":"","fpage":"394","highCitedState":"","htmlCount":21,"htmlFile":"","id":"70b06c94-7548-42ce-8585-b1c86ee9c5ae","issnPpub":"1000-0518","issue":"4","journalPublishId":"yyhx