Citation: Jing Zeng a, Yuan Li a, Jia-jing Li b, Rui Wang c, Bin He a, Yu Nie a, Xiang-lin Luo c, Zhi-rong Zhang d, Zhong-wei Gu a. INCLUSION COMPLEX FORMATION BETWEEN α-CYCLODEXTRIN AND BIODEGRADABLE COMBLIKE COPOLYMERS WITH POLY(α,β-MALIC ACID) BACKBONES AND mPEG SIDE CHAINS[J]. Chinese Journal of Polymer Science, ;2009, 27(5): 729-737. shu

INCLUSION COMPLEX FORMATION BETWEEN α-CYCLODEXTRIN AND BIODEGRADABLE COMBLIKE COPOLYMERS WITH POLY(α,β-MALIC ACID) BACKBONES AND mPEG SIDE CHAINS

Received Date: 27 August 2008
Revised Date: 7 November 2008

Inclusion complexes (ICs) composed of α-cyclodextrins (α-CD) and biodegradable comblike copolymers with poly(α,β-malic acid) (PMA) backbones and methylated poly(ethylene glycol) (mPEG) side chains were prepared by the host-guest reaction. Two series of ICs with mPEG750 and mPEG2000 were prepared. The stoichiometry (EG/CD) of all the ICs in mPEG2000 series was 3.1, no matter what the graft degree was. While in mPEG750 series, the stoichiometry (EG/CD) was very different; it increased with the amount of mPEG decreasing. The decomposition temperatures of the fragments in ICs were closely related to graft degrees. The stack of α-CDs in ICs was a channel-type structure. The crystal of ICs was lamellar, and it could be reorganized to well-defined supermolecular structure.
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