Citation: Guo Dong ZHENG, Qing Da AN, Yu Wen LIU, Ying Jun WANG, Xi Zhang CAO. ELECTROCARBOXYLATION OF ORGANIC COMPOUNDS WITH CARBON DIOXIDE CATALYZED BY METALLOPORPHYRINS(Ⅱ)--ELECTROSYNTHESIS OF SOME ORGANIC COMPOUNDS WITH CO₂ CATALYZED BY CoTPP[J]. Chinese Chemical Letters, ;1992, 3(4): 265-266. shu

ELECTROCARBOXYLATION OF ORGANIC COMPOUNDS WITH CARBON DIOXIDE CATALYZED BY METALLOPORPHYRINS(Ⅱ)--ELECTROSYNTHESIS OF SOME ORGANIC COMPOUNDS WITH CO₂ CATALYZED BY CoTPP

Department of Chemistry Jilin University Changchun 130023

Received Date: 1 November 1991

Fund Project: This work is supported by the National Natural Science Foundation of China.

The catalyzation of CoTPP for electrocarboxylation of alkyl halides, alkenes and ketones with CO₂ are studied. The electrocarboxylation of these organic compounds with CO₂ in the presenec of catalyst can occur at more positive potential than that of no catalyst. The products of electrocarboxylation were identified by UV, IR and GC-MS. The electrocarboxylation mechanisms of different organic compounds are discussed
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