Citation: Yu Lin JIANG, Ying Cheng LI, Bao Gong YANG, Da Bin GAO, Ji Ye TAN, Yun Cheng YUAN. Facile Bromination of Aromatic Ethers with Quaternary Ammonium Bromide and Iodosylbenzene[J]. Chinese Chemical Letters, ;1998, 9(1): 7-9. shu

Facile Bromination of Aromatic Ethers with Quaternary Ammonium Bromide and Iodosylbenzene

a Department of Chemistry, The University of Adelaide, Adelaide, South Australia 5005;
b Shanghai Research Institute of Petrochemical Technology, Shanghai 201208;
c School of Chemical Engineering, Dalian University of Technology, Dalian 116012

Received Date: 23 July 1997

Aromatic ethers were conveniently brominated with quaternary ammonium bromide and iodosylbenzene in glacial acetic acid under mild conditions to give the corresponding monobromo-aromatic ethers in nearly quantitative yields.
- bromination,
- aromatic ether,
- quaternary ammonium bromide,
- iodosylbenzene
1. [1]
  Leichen Wang , Anqing Mei , Na Li , Xiaohong Ruan , Xu Sun , Yu Cai , Jinjun Shao , Xiaochen Dong . Aza-BODIPY dye with unexpected bromination and high singlet oxygen quantum yield for photoacoustic imaging-guided synergetic photodynamic/photothermal therapy. Chinese Chemical Letters, 2024, 35(6): 108974-. doi: 10.1016/j.cclet.2023.108974
2. [2]
  Xiaojuan Lv , Yuting Dong , Hongliang Huang , Dariusz W. Szczepanik , Naoki Aratani , Takahisa Ikeue , Feng Chen , Tao Zhang , Fengxian Qiu , Toshiharu Teranishi , Songlin Xue . Local aromatic ring cleaves the global aromatic ring in hexaphyrin(2.1.2.1.2.1). Chinese Chemical Letters, 2025, 36(7): 110435-. doi: 10.1016/j.cclet.2024.110435
3. [3]
  Hai-Ying Yu , Yu-Wei Huang , Li-Ping Lin , Ren-Xiang Tan . Unprecedented diphenyl ether hybrids and spiro-diphenyl ether with antioxidant activity from Aspergillus sp. F1-8A associated with toad venom. Chinese Chemical Letters, 2026, 37(2): 111121-. doi: 10.1016/j.cclet.2025.111121
4. [4]
  Xiao Zhu , Yanbing Mo , Jiawei Chen , Gaopan Liu , Yonggang Wang , Xiaoli Dong . A weakly-solvated ether-based electrolyte for fast-charging graphite anode. Chinese Chemical Letters, 2024, 35(8): 109146-. doi: 10.1016/j.cclet.2023.109146
5. [5]
  Jinjie Lu , Qikai Liu , Yuting Zhang , Yi Zhou , Yanbo Zhou . Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water. Chinese Chemical Letters, 2024, 35(9): 109406-. doi: 10.1016/j.cclet.2023.109406
6. [6]
  Zhi-Peng Bao , Hefei Yang , Ru-Han A , Yuanrui Wang , Xiao-Feng Wu . Carbonylative five-component synthesis of amides and esters with α-quaternary carbon center. Chinese Chemical Letters, 2025, 36(11): 111150-. doi: 10.1016/j.cclet.2025.111150
7. [7]
  Yuanjiao Liu , Xiaoyang Zhao , Songyao Zhang , Yi Wang , Yutuo Zheng , Xinrui Miao , Wenli Deng . Site-selection and recognition of aromatic carboxylic acid in response to coronene and pyridine derivative. Chinese Chemical Letters, 2024, 35(8): 109404-. doi: 10.1016/j.cclet.2023.109404
8. [8]
  Hong Zhang , Cui-Ping Li , Li-Li Wang , Zhuo-Da Zhou , Wen-Sen Li , Ling-Yi Kong , Ming-Hua Yang . Asperochones A and B, two antimicrobial aromatic polyketides from the endophytic fungus Aspergillus sp. MMC-2. Chinese Chemical Letters, 2024, 35(9): 109351-. doi: 10.1016/j.cclet.2023.109351
9. [9]
  Dongying Fu , Lin Pan , Yanli Ma , Yue Zhang . Bilayered Dion–Jacobson lead-iodine hybrid perovskite with aromatic spacer for broadband photodetection. Chinese Chemical Letters, 2025, 36(2): 109621-. doi: 10.1016/j.cclet.2024.109621
10. [10]
  Jieshuai Xiao , Yuan Zheng , Yue Zhao , Zhuangzhi Shi , Minyan Wang . Asymmetric Nozaki-Hiyama-Kishi (NHK)-type reaction of isatins with aromatic iodides by cobalt catalysis. Chinese Chemical Letters, 2025, 36(5): 110243-. doi: 10.1016/j.cclet.2024.110243
11. [11]
  Laiyang ZHU , Xuze PAN , Xiaoying ZHANG , Xinyu XU , Shiheng LI , Fajin CAI , Yifan WANG , Qingxia YAO , Yi QIU , Jie SU . Synthesis of stable and porous bimetallic Ti-MOF for photocatalytic oxidation of aromatic sulfides to sulfoxides. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2115-2126. doi: 10.11862/CJIC.20250139
12. [12]
  Yunhao Guan , Xia Peng , Rong Fan , Xiaoying Feng , Hongguang Du , Jiajing Tan . Precise synthesis of ortho-deuterated aromatic derivatives: An arylthianthrenium salt-based platform approach. Chinese Chemical Letters, 2026, 37(1): 111132-. doi: 10.1016/j.cclet.2025.111132
13. [13]
  Zong-Yi Zhang , Xin Wang , Ying Li , Yuan Gao , Yao-Yue Fan , Jian-Min Yue , Jin-Xin Zhao . Isolation of two novel terpenoid skeletons from Croton laui, an aromatic norsesterterpenoid and a highly rearranged neo-clerodane diterpenoid. Chinese Chemical Letters, 2026, 37(2): 110951-. doi: 10.1016/j.cclet.2025.110951
14. [14]
  Feng Wu , Yuanjiu Xiao , Mengran Wei , Guoqiang Wang , Jian-Jun Feng . Lewis acid catalyzed enantioselective dearomative (3+2) cycloaddition of aromatic N-heterocycles with bicyclobutanes. Chinese Chemical Letters, 2026, 37(3): 111963-. doi: 10.1016/j.cclet.2025.111963
15. [15]
  Xindi Yang , Cunli Wang , Dongdong Wang , Haijuan Qin , Kuoxi Xu , Guangyan Qing . High efficiency detection of Zn²⁺ through the improved electron density of aromatic π-conjugated bridges. Chinese Chemical Letters, 2026, 37(4): 111215-. doi: 10.1016/j.cclet.2025.111215
16. [16]
  Chang Xu , Mengfan Luo , Jia Zhao , Jialong Yin , Can Feng , Heng Zhang , Peng Zhou , Zhaokun Xiong , Bo Lai . Ferrate(Ⅵ) combined with sulfur(Ⅳ) as an effective process for aromatic organoarsenic degradation: Essential role of Fe(Ⅲ) flocs. Chinese Chemical Letters, 2026, 37(4): 111538-. doi: 10.1016/j.cclet.2025.111538
17. [17]
  Saima Perveen , Xicheng Wang , Tao Li , Linghua Wang , Shuai Zhang , Yizhao Ouyang , Xue Zhao , Liang Xu , Pengfei Li . Enantioconvergent reductive amidation of benzyl ammonium salts for synthesis of α-chiral amides. Chinese Chemical Letters, 2026, 37(1): 111779-. doi: 10.1016/j.cclet.2025.111779
18. [18]
  Aonan Wang , Jingwen Dai , Yiming Guo , Fanghua Ning , Xiaoyu Liu , Sidra Subhan , Jiaqian Qin , Shigang Lu , Jin Yi . Imidazolium bromide based dual-functional redox mediator for the construction of dendrite-free Li-CO₂ batteries. Chinese Chemical Letters, 2025, 36(7): 110186-. doi: 10.1016/j.cclet.2024.110186
19. [19]
  Tingting Huang , Zhuanlong Ding , Hao Liu , Ping-An Chen , Longfeng Zhao , Yuanyuan Hu , Yifan Yao , Kun Yang , Zebing Zeng . Electron-transporting boron-doped polycyclic aromatic hydrocarbons: Facile synthesis and heteroatom doping positions-modulated optoelectronic properties. Chinese Chemical Letters, 2024, 35(4): 109117-. doi: 10.1016/j.cclet.2023.109117
20. [20]
  Xiang Huang , Dongzhen Xu , Yang Liu , Xia Huang , Yangfan Wu , Dongmei Fang , Bing Xia , Wei Jiao , Jian Liao , Min Wang . Asymmetric synthesis of difluorinated α-quaternary amino acids (DFAAs) via Cu-catalyzed difluorobenzylation of aldimine esters. Chinese Chemical Letters, 2024, 35(12): 109665-. doi: 10.1016/j.cclet.2024.109665

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1386)
HTML views(92)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return