Citation: Xiu Zhong ZHOU, Bai Quan WANG, Shan Sheng XU. SYNTHESIS,STRUCTURE AND THERMOREANGEMENT OF TRTRA METHYLDISILANDIYL BIS(1-INDENYL) TETRACARBONYL DI-IRON[J]. Chinese Chemical Letters, ;1995, 6(10): 897-898. shu

SYNTHESIS,STRUCTURE AND THERMOREANGEMENT OF TRTRA METHYLDISILANDIYL BIS(1-INDENYL) TETRACARBONYL DI-IRON

Department of Chemistry, Nankai University, Tianjin 300071

Received Date: 31 March 1995

Fund Project: This research was supported by the National Natural Science Foundation of China.

The title compound (Me₂SiSiMe₂)[η⁵-1-indenyl)Fe(CO)]₂(μ-CO)₂(1) was prepared by the reaction of 1.2-bis(1-indenyl)tetramethyldisilane and Fe(CO)₅ in relluxing heptane.1 in refluxing xylene can be converted into [Me₂Si(η⁵-1-indenyl) Fe(CO)₂]₂(2).The pure trans isomer 2t was obtained and its crystal and molecular structure was determined by X-ray diffraction.
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