Citation: Yang Fu MING, Qian Hong WU, Yi CAO. STUDIES ON MECHANIS OF PHOTOSENSITIZED ISOMERIZATION OF NORBORNADIENE DERIVATIVES[J]. Chinese Chemical Letters, ;1990, 1(2): 161-164. shu

STUDIES ON MECHANIS OF PHOTOSENSITIZED ISOMERIZATION OF NORBORNADIENE DERIVATIVES

Institute of Photographic Chemistry, Academia Sinica, Beijing 100012

Received Date: 29 December 1989

Using acridine dyes as sensitizers,the photoisomerization of three norbornadiene derivatives was investigated.The valence isomerization of nor-bornadiene derivatives (Ⅰ_a,Ⅰ_b,Ⅰ_c) gave their corresponding isomers of quadri-cyclane (Ⅱ_a,Ⅱ_b,Ⅱ_c) operating with relatively high efficiency in an electron transfer mode.Their quantum yields of isomerization were determined and the reaction mechanism was discussed.
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