Citation: Li Hua LIU, Zhi Qiang LIU, Zhu Qing GONG. Reactivity Ratios of Diethyldiallylammonium Chloride with Acrylamide or Acrylic Acid[J]. Chinese Chemical Letters, ;2006, 17(11): 1523-1526. shu

Reactivity Ratios of Diethyldiallylammonium Chloride with Acrylamide or Acrylic Acid

1.
College of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201;
2.
Metallurgical Physical Chemistry Institute, Central South University, Changsha 410083

Received Date: 15 February 2006

Fund Project: This work was supported by the Development and Evolution Program of DH-361.

The compositions of copolymers of diethyldiallylammonium chloride (DEDAAC) with acrylamide (AM), acrylic acid (AA) or sodium acrylic acid (NaAA) at low conversion were determined by elemental analysis, and the reactivity ratios of monomers in copolymerization were obtained by Kelen-Tudos method. The results showed that the reactivity ratios r_DE and r_AM are 0.31 and 5.27 for DEDAAC with AM, r_DE and r_AA are 0.28 and 5.15 for DEDAAC with AA, and r_DE and r_NaAA are 0.40 and 3.97 for DEDAAC with NaAA, respectively. The copolymerizations for DEDAAC with AM, AA or NaAA are non-ideal copolymerization and the products are random copolymers.
- Diethyldiallylammonium chloride (DEDAAC),
- acrylamide (AM),
- acrylic acid (AA),
- copolymerization,
- reactivity ratios
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