Citation: Chu Chi TANG, Mian Ji ZHANG, Fu Peng MA, Zhen LI. STUDIES ON CHIRAL THIOPHOSPHORIC ACIDS AND THEIR DERIVATIVES 11.——THE RESOLUTION OF O-METHYL O-PHENYL THIOPHOSPHORIC ACID AND ABSOLUTE CONFIGURATIONS OF ITS OPTICAL ISOMERS[J]. Chinese Chemical Letters, ;1993, 4(11): 949-950. shu

STUDIES ON CHIRAL THIOPHOSPHORIC ACIDS AND THEIR DERIVATIVES 11.——THE RESOLUTION OF O-METHYL O-PHENYL THIOPHOSPHORIC ACID AND ABSOLUTE CONFIGURATIONS OF ITS OPTICAL ISOMERS

Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071

Received Date: 24 August 1993

Fund Project: This project was supported by National Natural Science Foundation of China.

Racemic O-methyl O-pheayl thiophosphoric acid 1 has been successfully resolved through its quinine and brucine salts in methanol solution by fractional crystallization. The absolute configurations of the optically active 1 have been established as (+)-R-1 and (-)-S-1 by chemical correlation.
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