Citation: Sheng Yi ZHANG, Yu Peng TIAN. Synthesis,Crystal Structure and Electrochemical Properties of 2-Chlorobenzaldehyde Thiosemicarbazone[J]. Chinese Chemical Letters, ;1997, 8(5): 459-460. shu

Synthesis,Crystal Structure and Electrochemical Properties of 2-Chlorobenzaldehyde Thiosemicarbazone

Sheng Yi ZHANG ^a,b ,
Yu Peng TIAN ^a,b

a Department of chemistry, Anhui University, Hefei 230039;
b Coordination Chemistry, Institute State Key Laboratory of Naning University, Nanjing 210093

Received Date: 7 January 1997

The title compound crystallized in space group P2₁/c with Z=4,in a unit cell of dimensions,a=12.964(4),b=5.131(5),c=14.970(1)Å;V=9331(1)Å³,Dc=1.429gcm^-3,μ=0.541mm^-1,R=0.045,Rw=0.059.The equilibrium constant of the ligand with CdBr₂ was obtained by polarographic method.Crystal structure determination revealed that the molecule is in transconformation and non-hydrogen atoms of the molecule are in one plane except N(3) atom.
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