Citation: Shuang Hui LUO, Hui Ming JMNG, You Cheng LIU, Qing Xiang GUO. A Study on the Driving Force for Binding of Benzene Derivatives by α-and β-Cyclodextrin[J]. Chinese Chemical Letters, ;1998, 9(5): 463-464. shu

A Study on the Driving Force for Binding of Benzene Derivatives by α-and β-Cyclodextrin

1.
National Laboratory of Applied organic Chemistry, Lanzhou University, Lanzhou 730000;
2.
Department of Chemistry, University of Science and Technology of China, Hefei 230026

Received Date: 29 December 1997

Fund Project: This work was supported by the NNSF (Grant No, 29572067).

A three-dimensional diagram shows that the association constants (K_a) for the inclusion of a- and β-CD with substituted benzene are mainly correlated with the molar refraction (R_m) and hydrophobic constant (π_x)of the substituents of guest compounds. It reveals that the inclusion of cyclodextrin with the substituted benzene is dominantly driven by van der Waals forces and hydrophobic interactions.
- benzene derivatives,
- cyclodextrin,
- driving force,
- inclusion complexation
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