Citation: Ya Guang CHEN, Lun Yu QU, Song Chun JIN, Yong Hua LIN. STRUCTURE OF POTASSIUM α-TRIVANADOENNEATUNGSTOGERMANATE α-K₃H₄GeW₉V₃ O₄₀·8H₂O[J]. Chinese Chemical Letters, ;1992, 3(7): 555-558. shu

STRUCTURE OF POTASSIUM α-TRIVANADOENNEATUNGSTOGERMANATE α-K₃H₄GeW₉V₃ O₄₀·8H₂O

a Department of Chemistry, Northeast Normal University, Changchun 130024;
b Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022

Received Date: 22 May 1991

Fund Project: The project is supported by the National Natural Science Foundation of China.

The complex K₃H₄GeW₉V₃O₄₀·8H₂O crystallized in a monocliinie system with space group P2, Mr=2784.67, a=11.099(3), b=16.452(4), c=13.534(4), Å,β=108.14°, Z=2,V=2348.49 Å³, F(000)=2456, μ=239.7cm^-1, De=3.932 g/cm³. The final R=0.083 for 4528 non-zero reflexions. The structure of anions GeW₉V₃O₄₀^9- and GeW₉O₃₄^10- belongs to A-α-type.
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