Citation: Shu Tang LIU, Xiang HU, Qi Wang LIU, Wen Tao ZHANG. SYNTHESIS AND STRUTURE OF THE FIRST INTERSTITIAL μ₇-S CLUSTER Co₇(μ₇-S)(μ₄-PSEt)(μ-SEt)₂(μ-CO)₂(CO)₁₂[J]. Chinese Chemical Letters, ;1991, 2(4): 335-338. shu

SYNTHESIS AND STRUTURE OF THE FIRST INTERSTITIAL μ₇-S CLUSTER Co₇(μ₇-S)(μ₄-PSEt)(μ-SEt)₂(μ-CO)₂(CO)₁₂

Department of Chemistry, Inner Mongolia University, Huhhot 010021

Received Date: 21 January 1991

Fund Project: Support for this research by National Natural Science Foundation of China and by Fuzhou Research Laboratory of Structural Chemistry is gratefully acknowledged.

The reaction of Co₂(CO)₈ with EtSPCl₂ gives a new crystal like compound Co₇(μ₇-S)(μ₄-PSEt)(μ-SEt)₂(μ-CO)₂(CO)₁₂,whose structure has been determined by single crystal x-ray diffraction.This special compound reveals some new features in cluster chemistry¹:The fragmentation of a ligand precursor EtSPCl₂ yieldsthree kinds of fragments,μ₇-S,μ₄-PSEt and μ-SEt,which are ligands in the same cluster molecule.There is a new type of bridging S presented——A μ₇-S atom is interspaced into seven Co core.
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