Citation: Ren-ren Wang, Jia-qin Wang, Ce Luo, Zhe Zhang, Bi-tao Su, Zi-qiang Lei. EFFECT OF MORPHOLOGICAL STRUCTURE OF AMINOMETHYL POLYSTYRENE RESIN ON THE CATALYTIC PROPERTIES OF POLYMER-SUPPORTED RUTHENIUM COMPLEXES[J]. Chinese Journal of Polymer Science, ;2009, 27(1): 93-100. shu

EFFECT OF MORPHOLOGICAL STRUCTURE OF AMINOMETHYL POLYSTYRENE RESIN ON THE CATALYTIC PROPERTIES OF POLYMER-SUPPORTED RUTHENIUM COMPLEXES

Received Date: 24 October 2007
Revised Date: 7 December 2007

Polymer-supported ruthenium complexes #9413;-Phen-Ru-①, #9413;-Phen-Ru-②, #9413;-Phen-Ru-③, #9413;-Phen-Ru-④, #9413;-Phen-Ru-⑤, #9413;-Phen-Ru-⑥ and #9413;-Phen-Ru-⑦ were prepared using aminomethyl polystyrenes of different morphological structures as supports. A variety of alcohols were oxidized efficiently into the corresponding ketones, carboxylic acids or aldehydes with iodosylbenzene (PhIO) catalyzed by aminomethyl polystyrene-supported ruthenium complexes under mild reaction conditions in acetonitrile. The influences of morphological structure of the polymer supporters on the catalytic properties of these metal complexes were investigated in detail.
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