Citation: . SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*[J]. Chinese Journal of Polymer Science, ;2001, 19(1): 1-6. shu

SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*

Received Date: 29 February 2000

A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer, 3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS), was synthesized by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (Cp2PtC12) catalyst in high yield. The synthesized polynitroorganosiloxane, which has potential application as a precursor for synthesizing advanced functional polymers, was characterized by FTIR, 1H-NMR, 13C-NMR, 29Si-NMR, vapor pressure osmometry (VPO) and gel permeation chromatography (GPC).
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