Citation:
Xiu Ling ZHU, Xi Gao JIAN, Rui Ling WANG. Novel Polyamides Containing Biphenyl-phthalazinone Moieties[J]. Chinese Chemical Letters,
;2001, 12(6): 517-518.
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A novel diamine monomer 2H-(4-aminophenyl)-4-[4-(4-aminophenoxy) biphenyl]-phthalazinone 1 containing aza hetero cycle was synthesized and utilized for preparation of new high molecular weight aromatic polyamides with various aromatic dicarboxylic acids with the inherent viscosity of 0.50~1.62 g/dL. These polyamides had rather high glass transition temperatures of 327~356℃ and their structure was confirmed by IR, 1H NMR and MS. They are readily soluble in polar solvents such as NMP, DMF etc. and easily cast into tough, flexible films.
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Keywords:
- Polyarylamide,
- biphenyl-phthalazinone,
- solubility,
- thermostability.
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