Citation: Peng JIANG, Shi Jie LU. Asymmetric Catalytic Hydrogenation Using Rhodium Diphosphinites Derived From D-glucose and D-mannitol[J]. Chinese Chemical Letters, ;2000, 11(7): 587-588. shu

Asymmetric Catalytic Hydrogenation Using Rhodium Diphosphinites Derived From D-glucose and D-mannitol

Peng JIANG ,
Shi Jie LU

State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000

Received Date: 23 November 1999
Revised Date: 14 April 2000

Three diphosphinites were synthesized for preparing rhodium-diphosphinite complexes. The complexes were used for asymmetric catalytic hydrogenation of amino acid precursor α-acetamidocinnamic acid and its methyl ester. With all complexes, D-amino acid is the most abundant product.
- Asymmetric catalysis hydrogenation,
- rhodium diphosphinites,
- α-acetamidocinnic acid
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