Citation: Kang Ying LI, Zheng Hong ZHOU, Chi Hung YEUNG, Chu Chi TANG. A Chiral Phosphorous Derivatizing Agent for the Determination of the Enantiomeric Excess of Chiral Alcohols, Amines by ³¹p NMR[J]. Chinese Chemical Letters, ;2001, 12(10): 907-908. shu

A Chiral Phosphorous Derivatizing Agent for the Determination of the Enantiomeric Excess of Chiral Alcohols, Amines by ³¹p NMR

1.
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071;
2.
Laboratory of Chiral Technology and Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong

Received Date: 21 March 2001

Fund Project: We are very grateful for the financial support of the National Natural Science Foundation of China (No.29872016) and the Hong Kong Polytechnic University ASD Fund.

A chiral phosphorous derivatizing agent prepared from PCl₃ and (S)-BINOL was described. It is used to determine the enantiomeric excess of chiral alcohols and amines by ³¹p NMR.
- Chiral phosphorous,
- derivation,
- chiral alcohols,
- chiral amines,
- enantiomeric excess,
- asymmetric induction
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