Citation: Shao Kai JIANG, Xian Yuan WANG, Guang Nian LI. HYDROXYLATION OF n-HEXANE CATALYZED BY SUPPORTED Mn (Ⅲ)-PORPHYRIN COMPLEXES[J]. Chinese Chemical Letters, ;1992, 3(7): 503-506. shu

HYDROXYLATION OF n-HEXANE CATALYZED BY SUPPORTED Mn (Ⅲ)-PORPHYRIN COMPLEXES

a Chengdu Institute of Organic Chemistry, Academia Sinica, Chengdu 610015;
b Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai 200032

Received Date: 5 December 1991

Fund Project: Thanks to the National Natural Science Foundation of China for the financial support.

Water-soluble Mn (Ⅲ)-porphyrins supported on various carriers as monooxygenase-like catalysts were used for n-Hexane hydroxylation by PhIO. The hydroxylation yields and XPS measurement of the catalysts indicate that the carriers containing-OH groups have favorable steric and electronic effect on Mn-porphyrins. Some influencing factors and the role of carriers are discussed.
1. [1]
  Chengyao Zhao , Jingyuan Liao , Yuxiang Zhu , Yiying Zhang , Lianjie Zhai , Junrong Huang , Hengzhi You . Polystyrene-supported phosphoric-acid catalyzed atroposelective construction of axially chiral N-aryl benzimidazoles. Chinese Chemical Letters, 2025, 36(6): 110337-. doi: 10.1016/j.cclet.2024.110337
2. [2]
  Huihua GONG , Tianhua CUI , Li JI , Jichuan ZHANG , Liyuan ZHANG , Yan CHEN , Zhenye WANG , Jiaqi XU , Ruixiang LI . Hydrogenation of CO₂ to formate catalyzed by N-heterocyclic carbene-nitrogen-phosphine chelated iridium(Ⅰ) complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2609-2620. doi: 10.11862/CJIC.20250170
3. [3]
  Huanyu Liu , Gang Yu , Ruoyao Guo , Hao Qi , Jiayin Zheng , Tong Jin , Zifeng Zhao , Zuqiang Bian , Zhiwei Liu . Direct identification of energy transfer mechanism in Ce^Ⅲ-Mn^Ⅱ system by constructing molecular heteronuclear complexes. Chinese Chemical Letters, 2025, 36(2): 110296-. doi: 10.1016/j.cclet.2024.110296
4. [4]
  Yuwei Liang , Jianwei Huang , Zhiqiang Zhang , Qinghong Yang , Aiwen Lei , Hong Yi . Electrochemical Mn-catalyzed nitrogenation of alkynes to nitriles via C≡C bonds cleavage. Chinese Chemical Letters, 2026, 37(4): 111166-. doi: 10.1016/j.cclet.2025.111166
5. [5]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
6. [6]
  Shanyuan Bi , Jin Zhang , Dengchao Peng , Danhong Cheng , Jianping Zhang , Lupeng Han , Dengsong Zhang . Improved N₂ selectivity for low-temperature NO_x reduction over etched ZSM-5 supported MnCe oxide catalysts. Chinese Chemical Letters, 2025, 36(5): 110295-. doi: 10.1016/j.cclet.2024.110295
7. [7]
  Shaojie Ding , Henan Wang , Xiaojing Dai , Yuru Lv , Xinxin Niu , Ruilian Yin , Fangfang Wu , Wenhui Shi , Wenxian Liu , Xiehong Cao . Mn-modulated Co–N–C oxygen electrocatalysts for robust and temperature-adaptative zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100302-100302. doi: 10.1016/j.cjsc.2024.100302
8. [8]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
9. [9]
  Hongchao Wang , Wei Hao , Haowei Wu , Qianyu Ding , Yu Wei , Hu Zhao , Shuzhou Li , Hanying Li , Jia Zhu . Rational design of n-type organic thermoelectric materials: Insights from C_nBTBT–F_mTCNQ charge-transfer complexes. Chinese Chemical Letters, 2026, 37(2): 111933-. doi: 10.1016/j.cclet.2025.111933
10. [10]
  Chong Tang , Zhong Qiu , Chen Li , Tengfei Zhang , Renhong Chen , Yifa Sheng , Xinhui Xia , Yongqi Zhang , Jun Liu . Rational synthesis of vertical graphene supported TiN@N-Li₄Ti₅O₁₂ as advanced high-rate electrodes for lithium-ion batteries. Chinese Chemical Letters, 2025, 36(11): 110589-. doi: 10.1016/j.cclet.2024.110589
11. [11]
  Yu Peng , Yue Wang , Tian-Jiao Chen , Jing-Jing Chen , Jin-Ling Yang , Ting Gong , Ping Zhu . A fungal CYP from Beauveria bassiana with promiscuous steroid hydroxylation capabilities. Chinese Chemical Letters, 2024, 35(5): 108818-. doi: 10.1016/j.cclet.2023.108818
12. [12]
  Feng Wu , Yuanjiu Xiao , Mengran Wei , Guoqiang Wang , Jian-Jun Feng . Lewis acid catalyzed enantioselective dearomative (3+2) cycloaddition of aromatic N-heterocycles with bicyclobutanes. Chinese Chemical Letters, 2026, 37(3): 111963-. doi: 10.1016/j.cclet.2025.111963
13. [13]
  Chaochao Jin , Kai Li , Jiongpei Zhang , Zhihua Wang , Jiajing Tan . N,O-Bidentated difluoroboron complexes based on pyridine-ester enolates: Facile synthesis, post-complexation modification, optical properties, and applications. Chinese Chemical Letters, 2024, 35(9): 109532-. doi: 10.1016/j.cclet.2024.109532
14. [14]
  Le Zhang , Hui-Yu Xie , Xin Li , Li-Ying Sun , Ying-Feng Han . SOMO-HOMO level conversion in triarylmethyl-cored N-heterocyclic carbene-Au(I) complexes triggered by selecting coordination halogens. Chinese Chemical Letters, 2024, 35(11): 109465-. doi: 10.1016/j.cclet.2023.109465
15. [15]
  Dai-Huo Liu , Ao Wang , Hong-Yan Lü , Xing-Long Wu , Dan Luo , Wen-Hao Li , Jin-Zhi Guo , Haozhen Dou , Qianyi Ma , Zhongwei Chen . In situ constructing (MnS/Mn₂SnS₄)@N,S-ACTs heterostructure with superior Na/Li-storage capabilities in half-cells and pouch full-cells. Chinese Chemical Letters, 2024, 35(11): 109285-. doi: 10.1016/j.cclet.2023.109285
16. [16]
  Rui LIU , Xinjun ZHOU , Tao WANG . Photocatalytic degradation performance of tetracycline by MOF-74-Mn/g-C₃N₄ Z-type heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1796-1804. doi: 10.11862/CJIC.20250033
17. [17]
  Jiahong WANG , Zekun XU , Tianjiao LU , Jinming HUANG . Performance of N, Mn doped semi-coke activated carbon catalyzed ozone oxidation for the degradation of tetracycline hydrochloride in water. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2549-2560. doi: 10.11862/CJIC.20250120
18. [18]
  Hong-Tao Ji , Yu-Han Lu , Yan-Ting Liu , Yu-Lin Huang , Jiang-Feng Tian , Feng Liu , Yan-Yan Zeng , Hai-Yan Yang , Yong-Hong Zhang , Wei-Min He . Nd@C₃N₄-photoredox/chlorine dual catalyzed synthesis and evaluation of antitumor activities of 4-alkylated sulfonyl ketimines. Chinese Chemical Letters, 2025, 36(2): 110568-. doi: 10.1016/j.cclet.2024.110568
19. [19]
  Jingyao Yu , Zhuoran Yang , Jian Jiang , Mengshu Xu , Chunyu Yang , Zhuo Li , Wei Guo . Engineering asymmetric electronic structures in Fe-N-S-C nanozymes for dual enzyme-catalyzed-induced ferroptosis and enhanced antitumor efficacy. Chinese Chemical Letters, 2026, 37(3): 111693-. doi: 10.1016/j.cclet.2025.111693
20. [20]
  Yun Zhou , Geqian Fang , Haiyan Wang , Wenjun Yu , Chun Zhu , Jin-Xia Liang , Jian Lin . Non-covalent interactions between adsorbed •OH species and UiO-66-NH2 for methane hydroxylation. Chinese Journal of Structural Chemistry, 2025, 44(8): 100629-100629. doi: 10.1016/j.cjsc.2025.100629

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1348)
HTML views(20)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return