Citation: Xiao Bing LU, Yu Zhen PAN, Dong Feng JI, Ren HE. Catalytic Formation of Propylene Carbonate from Supercritical Carbon Dioxide/Propylene Oxide Mixture[J]. Chinese Chemical Letters, ;2000, 11(7): 589-592. shu

Catalytic Formation of Propylene Carbonate from Supercritical Carbon Dioxide/Propylene Oxide Mixture

Laboratory of Comprehensive utilization for carbonaceous resources, Dalian University of Technology, Dalian 116012

Received Date: 6 December 1999
Revised Date: 10 April 2000

Propylene carbonate was synthesized from supercritical carbon dioxide (SC-CO₂)/propylene oxide mixture with phthalocyaninatoaluminium chloride (ClAlPc)/tetrabutylammon-ium bromide (n-Bu₄NBr) as catalyst. The high rate of reaction was attributed to rapid diffusion and the high miscibility of propylene oxide in SC-CO₂ under employed conditions. Various reaction periods present different formation rate of propylene carbonate, mainly due to the existence of phase change during the reaction. The experimental results demonstrate that SC-CO₂ could be used as not only an environmentally benign solvent but also a carbon precursor in synthesis.
- Supercritical carbon dioxide,
- propylene oxide,
- propylene carbonate,
- cycloaddition reaction
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