Citation: QIN Wei, HUANG Zhitang. AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS XIX:THE POLYMERIZATION OF SUBSTITUTED BENZONITRILES CATALYZED BY COBALTIC ACETYLACETONATE[J]. Chinese Journal of Polymer Science, ;1996, 14(3): 255-260. shu

AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS XIX:THE POLYMERIZATION OF SUBSTITUTED BENZONITRILES CATALYZED BY COBALTIC ACETYLACETONATE

QIN Wei ,
HUANG Zhitang

Received Date: 17 January 1996

The polymerization kinetics of 4, 4'-biphenyldicarbonitrile and other substituted ben-zonitriles catalyzed by cobaltic acetylacetonate was studied. The structure of polymer ofdifferent substituted benzonitrile was also determined. It is found that the rate of polymeri-zation and the structure of polymer is greatly affected by the substituent of benzonitriles.
1. [1]
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2. [2]
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3. [3]
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4. [4]
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5. [5]
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7. [7]
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8. [8]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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