Citation: Ming Wu DING, Wen Fan HUNG, Hai Yang TU, Tian Jie WU. First Preparation and Reactivity of γ-Oxo Vinyliminophosphorane[J]. Chinese Chemical Letters, ;1997, 8(4): 289-290. shu

First Preparation and Reactivity of γ-Oxo Vinyliminophosphorane

a Institute of Organic Synthesis, Central China Normal University, Wuhan 430070;
b Center of Analysis and Testing, Central China Normal University, Wuhan 430070

Received Date: 7 January 1997

Fund Project: We acknowledge financial support of this work by the Natural Science Foundation of Hubei Province and the Dawn Plan of Science and Technology for Young Socientists of Wuhan City.

The γ-oxo vinyliminophosphorane 3 was prepared for the first time from the Staudinger reaction of vinyl azide 2 and triphenylphosphine.The reactivity of 3 was studied.
1. [1]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
2. [2]
  Xu-Hui Yue , Xiang-Wen Zhang , Hui-Min He , Lei Qiao , Zhong-Ming Sun . Synthesis, chemical bonding and reactivity of new medium-sized polyarsenides. Chinese Chemical Letters, 2024, 35(7): 108907-. doi: 10.1016/j.cclet.2023.108907
3. [3]
  Yuanjin Chen , Xianghui Shi , Dajiang Huang , Junnian Wei , Zhenfeng Xi . Synthesis and reactivity of cobalt dinitrogen complex supported by nonsymmetrical pincer ligand. Chinese Chemical Letters, 2024, 35(7): 109292-. doi: 10.1016/j.cclet.2023.109292
4. [4]
  Hai-Ling Wang , Zhong-Hong Zhu , Hua-Hong Zou . Structure and assembly mechanism of high-nuclear lanthanide-oxo clusters. Chinese Journal of Structural Chemistry, 2024, 43(9): 100372-100372. doi: 10.1016/j.cjsc.2024.100372
5. [5]
  Shaohua Zhang , Xiaojuan Dai , Wei Hao , Liyao Liu , Yingqiao Ma , Ye Zou , Jia Zhu , Chong-an Di . A first-principles study of the Nernst effect in doped polymer. Chinese Chemical Letters, 2024, 35(12): 109837-. doi: 10.1016/j.cclet.2024.109837
6. [6]
  Shiqi Xu , Zi Ye , Shuang Shang , Fengge Wang , Huan Zhang , Lianguo Chen , Hao Lin , Chen Chen , Fang Hua , Chong-Jing Zhang . Pairs of thiol-substituted 1,2,4-triazole-based isomeric covalent inhibitors with tunable reactivity and selectivity. Chinese Chemical Letters, 2024, 35(7): 109034-. doi: 10.1016/j.cclet.2023.109034
7. [7]
  Caixia Zhu , Qing Hong , Kaiyuan Wang , Yanfei Shen , Songqin Liu , Yuanjian Zhang . Single nanozyme-based colorimetric biosensor for dopamine with enhanced selectivity via reactivity of oxidation intermediates. Chinese Chemical Letters, 2024, 35(10): 109560-. doi: 10.1016/j.cclet.2024.109560
8. [8]
  Jumei Zhang , Ziheng Zhang , Gang Li , Hongjin Qiao , Hua Xie , Ling Jiang . Ligand-mediated reactivity in CO oxidation of yttrium-nickel monoxide carbonyl complexes. Chinese Chemical Letters, 2025, 36(2): 110278-. doi: 10.1016/j.cclet.2024.110278
9. [9]
  Min Fu , Ruihan Wang , Wenqiang Liu , Sen Zhou , Chunhong Zhong , Yaohao Li , Pan He , Xin Li , Shiying Shang , Zhongping Tan . Improved one-pot protein synthesis enabled by a more precise assessment of peptide arylthioester reactivity. Chinese Chemical Letters, 2025, 36(7): 110542-. doi: 10.1016/j.cclet.2024.110542
10. [10]
  Run-Han Li , Tian-Yi Dang , Wei Guan , Jiang Liu , Ya-Qian Lan , Zhong-Min Su . Evolution exploration and structure prediction of Keggin-type group IVB metal-oxo clusters. Chinese Chemical Letters, 2024, 35(5): 108805-. doi: 10.1016/j.cclet.2023.108805
11. [11]
  Ying Wang , Jiaqi Lv , Song Liang , Yingdong Xie , Yuan Tian , Dong Li , Hong-Ying Zang . Molecular iron-oxo clusters ameliorate sepsis via enhancing humoral immune response. Chinese Chemical Letters, 2025, 36(11): 111455-. doi: 10.1016/j.cclet.2025.111455
12. [12]
  Gui-Xin Yan , Er-Xia Chen , Jin-Xia Yang , Jian Zhang , and Qipu Lin . Chiral europium-organotin oxo-clusters with dual-emission circularly polarized luminescence. Chinese Journal of Structural Chemistry, 2025, 44(12): 100759-100759. doi: 10.1016/j.cjsc.2025.100759
13. [13]
  Liping GUO . Synthesis and crystal structure characterization of yttrium imido complex: The reactivity of 2-substituted-1-amino-o-carborane with yttrium dialkyl complex. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1409-1415. doi: 10.11862/CJIC.20250065
14. [14]
  Wen-Jun Xia , Yong-Jiang Wang , Yun-Fei Cao , Cai Sun , Xin-Xiong Li , Yan-Qiong Sun , Shou-Tian Zheng . A luminescent folded S-shaped high-nuclearity Eu₁₉-oxo-cluster embedded polyoxoniobate for information encryption. Chinese Chemical Letters, 2025, 36(2): 110248-. doi: 10.1016/j.cclet.2024.110248
15. [15]
  Hao-Nan Zhou , Lan-Yan Li , Hong-Bing Mo , Yi-Xin Li , Jun Yan , Chao Liu . Ligand-engineered octanuclear bismuth-oxo clusters with exposed active sites for enhanced CO₂-to-HCOOH electroreduction. Chinese Chemical Letters, 2025, 36(10): 111269-. doi: 10.1016/j.cclet.2025.111269
16. [16]
  Jinlian SHI , Xiaoru LIU , Zhongxuan XU . Ligand-directed construction of cobalt-oxo cluster-based organic frameworks: Structural modulation, semiconductor, and antiferromagnetic properties. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 45-54. doi: 10.11862/CJIC.20250196
17. [17]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
18. [18]
  Yueying Yang , Huiru Xie , Xinbo Yu , Yang Liu , Hui Wang , Hua Li , Lixia Chen . Design, synthesis and evaluation of the first DYRK1A degrader for promoting the proliferation of pancreatic β-cells. Chinese Chemical Letters, 2024, 35(11): 109570-. doi: 10.1016/j.cclet.2024.109570
19. [19]
  Kun Liu , Yulin Cong , Xiongfeng Luo , Meicun Yao , Zhiyong Xie , Hao Li . Utilizing bivalent aptamers as first DNA agonist to activate RTKs heterodimer of different families. Chinese Chemical Letters, 2025, 36(1): 109839-. doi: 10.1016/j.cclet.2024.109839
20. [20]
  Zhihao HE , Jiafu DING , Yunjie WANG , Xin SU . First-principles study on the structure-property relationship of AlX and InX (X=N, P, As, Sb). Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1007-1019. doi: 10.11862/CJIC.20240390

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1308)
HTML views(18)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return