Citation: Ying Min YU, Jin Hua FEI, Yi Ping ZHANG, Xiao Ming ZHENG. Immobilized Ruthenium Catalyst for Carbon Dioxide Hydrogenation[J]. Chinese Chemical Letters, ;2006, 17(8): 1097-1100. shu

Immobilized Ruthenium Catalyst for Carbon Dioxide Hydrogenation

1.
Institute of Catalysis, Zhejiang University, Hangzhou 310028;
2.
Department of Chemistry, Zhejiang Education Institute, Hangzhou 310012

Received Date: 19 December 2005

Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 20173048) and the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20030335068).

Three kinds of cross linked polystyrene resin (PS) supported ruthenium complexes were developed as catalysts for the synthesis of formic acid from carbon dioxide hydrogenation. Many factors, such as the functionalized supports, solvents and ligands, could influence their activities and reuse performances greatly. These immobilized catalysts also offer the industrial advantages such as easy separation.
- Immobilization,
- resin,
- supported Ru catalyst,
- hydrogenation,
- CO₂-expanded solvent
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