Citation: He Ping WU, Yuan Qi YIN, Kai Bei YU, Xiao Ying HUANG. A NOVEL SYNTHETIC METHOD FOR THE CLUSTERS FeCo₂CO₉-(RCCR)(R=MeO₂C,EtO₂C).X-RAY CRYSTAL STRUCTURE ANALYSES OF THE CLUSTERS FeCo₂CO₉(MeO₂CCCCO₂Me)andCo₄(CO)₁₀ -(EtO₂CCCCO₂Et)[J]. Chinese Chemical Letters, ;1996, 7(6): 585-588. shu

A NOVEL SYNTHETIC METHOD FOR THE CLUSTERS FeCo₂CO₉-(RCCR)(R=MeO₂C,EtO₂C).X-RAY CRYSTAL STRUCTURE ANALYSES OF THE CLUSTERS FeCo₂CO₉(MeO₂CCCCO₂Me)andCo₄(CO)₁₀ -(EtO₂CCCCO₂Et)

a Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;
b Chengdu Analysis Determination Center, Chinese Academy of Sciences, Chengdu,610041;
c Fuzhou Institute of Research on Structure of Matter, Chinese Academy of Sciences, State Key Laboratory of Structure Chemistry, Fuzhou, 350002

Received Date: 22 September 1995

Fund Project: This work is surported by Shanghai Organometallic Laboratory, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

A novel synthetic method for the clusters FeCo₂(CO)₉(RCCR)(R=MeO₂C,MeO₂C),which is the reaction of Co₄(CO)₁₀(RCCR) with Na₂[Fe(CO)₄],have been found by studying on the thermal reaction between RCCo₃(CO)₉ with Na₂[Fe(CO)₄].X-ray crystal structural determinations have been made for the clusters FeCo₂(CO)₉(MeO₂CCCCO₂Me) and Co₄(CO)₁₀(EtO₂CCCCO₂Et).
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