Citation: Shi Ming DONG, Duo Yuan WANG. THE LINEAR CORRELATIONS BETWEEN ELECTRONIC TRANSITION ENERGY AND HAMMETT CONSTANTS FOR THE SUBSTITUTED PORPHYRIN-LIKE MACROCYCLE[J]. Chinese Chemical Letters, ;1993, 4(3): 243-246. shu

THE LINEAR CORRELATIONS BETWEEN ELECTRONIC TRANSITION ENERGY AND HAMMETT CONSTANTS FOR THE SUBSTITUTED PORPHYRIN-LIKE MACROCYCLE

Institute of Photographic Chemistry, Academia Sinica, Beijing 100101

Received Date: 25 September 1992

Fund Project: This work is supported by NSPC

The properties of absorption spectra are presented and the linear correlations of Hammett constants with the 0-0 transition energy(Eo,o)of S₁←S^o,and the ratios of oscillator strength(f_a/f_e)are used to probe the interactions betwee π-electron of aromatic maerocycles or metal ion of complexes with the substituents on β-position of benzene ring for porphyrin-like maerocyclic compounds
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