Citation: Yan SUN, Jing Mei YIN, Da Bin GAO, Guang Yun ZHOU, Ying Ping JIA. Photopromoted Carbonylation of Alkyl Halides Under Ambient Conditions[J]. Chinese Chemical Letters, ;2003, 14(6): 575-578. shu

Photopromoted Carbonylation of Alkyl Halides Under Ambient Conditions

1.
Department of Chemistry & Technology, Dalian University of Technology, Dalian 116012;
2.
Department of Chemistry and Chemical Engineering, Dalian University, Dalian 116622

Received Date: 25 July 2002

Fund Project: We are indebted to the National Natural Science Foundations of China (No. 20172010,20242004), for the generous financial support

Photopromoted carbonylation of alkyl halides with carbon monoxide can be carried outunder ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts. Our preliminary work showed that alkyl halides can be transformed into alkene andalkane directly under irradiation, but the esters can not be transformed. It is assumed that thecarbonylation of alkyl halides may be proceeded in two ways.
- Photopromoted carbonylation,
- alkyl halides,
- carbon monoxide
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