Citation: Yi Lin CAO, Hong Lin LIU, Nian Yi CHEN. STUDIES ON THE ANIONIC SPECIES OF SODIUM ALUMINATE SOLUTIONS OF LOW CAUSTIC RATIOS[J]. Chinese Chemical Letters, ;1995, 6(10): 885-886. shu

STUDIES ON THE ANIONIC SPECIES OF SODIUM ALUMINATE SOLUTIONS OF LOW CAUSTIC RATIOS

1.
Department of Chemistry, Henan Normal University, Xinxiang 453002;
2.
Hong Lin LIU Nian Yi CHEN Shanghai Institute of Metallurgy, Academia Sinica, Shanghai 200050

Received Date: 10 March 1995

UV and Raman spectra were used in the studies of anionic species in sodium aluminate solutions.Two absorption peaks near 233nm and 270nm in UV spectra were found and assigned to Al(OH)₄ and [(HO)₃Al-O-Al(OH)₃]^2- respectively,while the results of Raman spectra measurements and quantum chemical calculations by using MNDO and DV-X_α methods were in good agreement with the above conclusions.
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