Citation: Can Xiong GUO, Yan LIU, Feng LI, Peng SUN, David G.EVANS, Xue DUAN. Fries Rearrangement of Phenyl Acetate over Solid Acid Catalyst[J]. Chinese Chemical Letters, ;2002, 13(1): 7-8. shu

Fries Rearrangement of Phenyl Acetate over Solid Acid Catalyst

The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029

Received Date: 2 April 2001

A silica-supported zirconium based solid acid (ZS) has been used as catalyst for the Fries rearrangement of phenyl acetate (PA).The catalyst showed a higher PA conversion activity and a much higher selectivity for o-hydroxyacetophenone (o-HAP) than for strongly acidic zeolite catalysts.The supported catalyst was characterized by XRD, IR, XPS, pyridine-TPD and the surface area measurements.The catalytic properties were influenced significantly by pretreatment temperature.
- Supported catalyst,
- solid acid ,
- Fries rearrangement,
- zirconium
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