Citation: Gen Liang LU, Yong Min ZHANG. Synthesis of α-Selenoesters and α-Thiolesters via Sm/SbCl₃ System in Aqueous Media[J]. Chinese Chemical Letters, ;1999, 10(8): 641-642. shu

Synthesis of α-Selenoesters and α-Thiolesters via Sm/SbCl₃ System in Aqueous Media

Department of Chemistry, Zhejiang University(Campus Xixi), Hangzhou 310028

Received Date: 24 March 1999

Fund Project: We thank the National Natural Science Foundation of China (Project No. 29872010 and 294938004). NSF of Zhejiang Province. China and the Laborartory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry. Chinese Academy of Sciences for financial support.

α-Selenoesters and α-thiolesters are synthesized via reactions of α-bromoesters with diselenides and disulfides promoted by Sm/SbCl₃ system in aqueous media in moderate to good yields.
- α-Selenoesters,
- α-thiolesters,
- samarium,
- antimony trichloride,
- aqueous media
1. [1]
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5. [5]
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19. [19]
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20. [20]
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