Citation: Tie Jun WANG, Zhao Hui MA, Mei Yu HUANG, Ying Yan JIANG. ELECTRON TRANSFER AGENT DEPENDENCY OF MONOOXYGENATION OF CYCLOHEXANE CATALYZED BY SILICA IMMOBILIZED N,N'-BIS[2-(BENZIMIDAZOLYLMETHYL)] AMINO FERROUS ACETATE COMPLEX[J]. Chinese Chemical Letters, ;1996, 7(1): 47-50. shu

ELECTRON TRANSFER AGENT DEPENDENCY OF MONOOXYGENATION OF CYCLOHEXANE CATALYZED BY SILICA IMMOBILIZED N,N'-BIS[2-(BENZIMIDAZOLYLMETHYL)] AMINO FERROUS ACETATE COMPLEX

Institute of Chemistry, Academia Sinica, Beijing, 100080

Received Date: 5 June 1995

Silica immobilized N,N'-bis[-2-(benzimidazolylmethyl)]amino-ferrous acetate complexes (Ⅳ) catalyzed monooxygenation of cyclohexane to cyclohexanol with the turnover number 8.4 (equivalent C%=11.2) under mild conditions.The methylene blue is the most effective electron transfer agent which can also regulate products distribution.The iron content of the polymer-supported complexes,the redox potentials and the concentration of methylene blue greatly affect the activity and selectivity of the complex (Ⅳ).
1. [1]
  Yun-Xin Huang , Lin-Qian Yu , Ke-Yu Chen , Hao Wang , Shou-Yan Zhao , Bao-Cheng Huang , Ren-Cun Jin . Biochar with self-doped N to activate peroxymonosulfate for bisphenol-A degradation via electron transfer mechanism: The active edge graphitic N site. Chinese Chemical Letters, 2024, 35(9): 109437-. doi: 10.1016/j.cclet.2023.109437
2. [2]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
3. [3]
  Fengzhi Wang , Ke Hu , Jinquan Chen , Zhubin Hu , Haitao Sun , Tony D. James , Yufang Xu , Xuhong Qian . Meta-amino substituted naphthalimides exhibit large charge transfer and strong N-H vibrations enabling use as ratiometric fluorescent probe. Chinese Chemical Letters, 2026, 37(1): 110971-. doi: 10.1016/j.cclet.2025.110971
4. [4]
  Qiuyue Lu , Min Shan , Jiaqi Yang , Zhongren Xu , Yueyue Lei , Wukun Liu . A dinuclear gold(I) complex with bis(N-heterocyclic carbene) ligands potentiated immune responses against liver cancer via ROS-driven endoplasmic reticulum stress and ferroptosis. Chinese Chemical Letters, 2025, 36(12): 110940-. doi: 10.1016/j.cclet.2025.110940
5. [5]
  Quanyou Guo , Yue Yang , Tingting Hu , Hongqi Chu , Lijun Liao , Xuepeng Wang , Zhenzi Li , Liping Guo , Wei Zhou . Regulating local electron transfer environment of covalent triazine frameworks through F, N co-modification towards optimized oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(1): 110235-. doi: 10.1016/j.cclet.2024.110235
6. [6]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
7. [7]
  Huihua GONG , Tianhua CUI , Li JI , Jichuan ZHANG , Liyuan ZHANG , Yan CHEN , Zhenye WANG , Jiaqi XU , Ruixiang LI . Hydrogenation of CO₂ to formate catalyzed by N-heterocyclic carbene-nitrogen-phosphine chelated iridium(Ⅰ) complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2609-2620. doi: 10.11862/CJIC.20250170
8. [8]
  Feng Wu , Yuanjiu Xiao , Mengran Wei , Guoqiang Wang , Jian-Jun Feng . Lewis acid catalyzed enantioselective dearomative (3+2) cycloaddition of aromatic N-heterocycles with bicyclobutanes. Chinese Chemical Letters, 2026, 37(3): 111963-. doi: 10.1016/j.cclet.2025.111963
9. [9]
  Lijun Liao , Yuhao Wang , Yanbo Li , Yingchun Chen , Ruting Yuan , Bo Wang , Tiancheng Zhuang , Guangquan Zhao , Wei Zhou . Synergy of electron-trapping centers and solid adsorption toward 100% suppression of toxic byproduct N₂O in photocatalytic NO reduction. Chinese Chemical Letters, 2026, 37(3): 111398-. doi: 10.1016/j.cclet.2025.111398
10. [10]
  Huixian Weng , Lefei Hu , Lei Hu , Yihan Zhou , Aohua Wang , Ning Wang , Wenzhe Li , Chunliu Zhu , Shiyan Guo , Miaorong Yu , Yong Gan . Corrigendum to "The complexation of insulin with sodium N-[8-(2-hydroxybenzoyl)amino]-caprylate for enhanced oral delivery: Effects of concentration, ratio, and pH" [Chinese Chemical Letters 33 (2022) 1889-1894]. Chinese Chemical Letters, 2025, 36(8): 111316-. doi: 10.1016/j.cclet.2025.111316
11. [11]
  Liping GUO . Synthesis and crystal structure characterization of yttrium imido complex: The reactivity of 2-substituted-1-amino-o-carborane with yttrium dialkyl complex. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1409-1415. doi: 10.11862/CJIC.20250065
12. [12]
  Fei Jin , Bolin Yang , Xuanpu Wang , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Facilitating efficient photocatalytic hydrogen evolution via enhanced carrier migration at MOF-on-MOF S-scheme heterojunction interfaces through a graphdiyne (CnH2n-2) electron transport layer. Chinese Journal of Structural Chemistry, 2023, 42(12): 100198-100198. doi: 10.1016/j.cjsc.2023.100198
13. [13]
  Shuang Zhao , Fei Jia , Kaibei Zhan , Rui-Xi Wang , Pengfei Tan , Lin Shen , Li-Ming Wu , Ling Chen . Amino substitution strategy achieves significant blue shift while preserving high optical anisotropy: A₂(H₃C₃N₄S₂)₂•H₂O (A =NH₄, K, Rb, Cs). Chinese Chemical Letters, 2026, 37(3): 110625-. doi: 10.1016/j.cclet.2024.110625
14. [14]
  Rui Hu , Yidan Qi , Xingyu Wang , Yunhui Yang , Congyang Wang . Titanium-promoted conversion of N₂ into N-methylimides. Chinese Chemical Letters, 2026, 37(1): 111197-. doi: 10.1016/j.cclet.2025.111197
15. [15]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
16. [16]
  Huifang Ma , Tao Xu , Saifei Yuan , Shujuan Li , Jiayao Wang , Yuping Zhang , Hao Ren , Shulai Lei . Interlayer interactions and electron transfer effects on sodium adsorption on 2D heterostructures surfaces. Chinese Chemical Letters, 2025, 36(8): 110219-. doi: 10.1016/j.cclet.2024.110219
17. [17]
  Yiyue Ding , Qiuxiang Zhang , Lei Zhang , Qilu Yao , Gang Feng , Zhang-Hui Lu . Exceptional activity of amino-modified rGO-immobilized PdAu nanoclusters for visible light-promoted dehydrogenation of formic acid. Chinese Chemical Letters, 2024, 35(7): 109593-. doi: 10.1016/j.cclet.2024.109593
18. [18]
  Hongchao Wang , Wei Hao , Haowei Wu , Qianyu Ding , Yu Wei , Hu Zhao , Shuzhou Li , Hanying Li , Jia Zhu . Rational design of n-type organic thermoelectric materials: Insights from C_nBTBT–F_mTCNQ charge-transfer complexes. Chinese Chemical Letters, 2026, 37(2): 111933-. doi: 10.1016/j.cclet.2025.111933
19. [19]
  Ruixue Liu , Xiaobing Ding , Qiwei Lang , Gen-Qiang Chen , Xumu Zhang . Enantioselective and divergent construction of chiral amino alcohols and oxazolidin-2-ones via Ir-f-phamidol-catalyzed dynamic kinetic asymmetric hydrogenation. Chinese Chemical Letters, 2025, 36(3): 110037-. doi: 10.1016/j.cclet.2024.110037
20. [20]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1473)
HTML views(21)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return