Citation: WAN MeiXiang, Li Ming, MI Xin, JIANG Qian, YE Peixian. THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*[J]. Chinese Journal of Polymer Science, ;1996, 14(1): 80-85. shu

THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*

Received Date: 3 August 1994

The fully oxidized state of polyaniline (PANI), pernigraniline (PN), was synthesizedby oxidation of the emeraldine base form of PANI dissolved in NMP solvent with m-chloroperoxybenzoic acid. The resulted PN was characterized by FTIR and UV-Visiblespectra. The third-order nonlinear optical properties of PN in concentrated sulfuric acid(PN/H2SO4) were measured by a degenerated four wave mixing (DFWM) method. The re-sults obtained suggest that the soliton-pair intermediate state associated with the degenerated state does not play a major role in the third order nonlinear optical properties of PANI.
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