Citation: Zhong Sheng JIN, Ge Cheng WEI, Yung Shing LIU, Gang DONG, Chun Ting SUN, Qi Jun HUANG, Fan YANG. MOLECULAR AND CRYSTAL STRUCTURES OF TETRANUCLEAR MOLYBDENUM CLUSTER[MO₄(μ3-O)₂O₄Cl2(o-CH₃C₆H₄COO)⁶][J]. Chinese Chemical Letters, ;1990, 1(3): 245-246. shu

MOLECULAR AND CRYSTAL STRUCTURES OF TETRANUCLEAR MOLYBDENUM CLUSTER[MO₄(μ3-O)₂O₄Cl2(o-CH₃C₆H₄COO)⁶]

a Changchun Institute of Applied Chemistry Chinese Academy of Science Changchun 130022 China;
b Department of Chemistry Jilin University Changchun 130023 China

Received Date: 19 March 1990

The new cluster[MO₄(μ3-O)₂O₄Cl2(o-CH₃C₆H₄COO)⁶]has been prepared by the reaction of molybdenum pentachloride and o-methylbenzoic acid.The crystal and molecular structures were determined by the X-ray diffraction method.It crystallizes in the orthorhombic space group Pnna with cell parameters:Mr=1361.6, a=13.792(4), b=17.957(3), c=20.974(9)Å , V=5194(2) 3, Z=4, Dc=1.74/cm³, F(OOO)=2704, μ(MoKα)=11.0/cm, R=0.074.
1. [1]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
2. [2]
  Xuan Pang , Leyan Nian , Yongzhang Wang , Chunmei Huang . Na2(C6H4NO3)2∙H2O: A promising ultraviolet nonlinear optical crystal with strong second-harmonic generation effect and large birefringence. Chinese Journal of Structural Chemistry, 2026, 45(4): 100847-100847. doi: 10.1016/j.cjsc.2025.100847
3. [3]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
4. [4]
  Jiaxin Zhang , Yingzhang Shi , Zhiwen Wang , Yujie Song , Dongpeng Yan . Photosynthesis of CH4 and H2O2 from CO2 and H2O over Pd/SnNb2O6 via strong metal-support interaction. Chinese Journal of Structural Chemistry, 2026, 45(5): 100866-100866. doi: 10.1016/j.cjsc.2026.100866
5. [5]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
6. [6]
  Aoyun Meng , Zhenhua Li , Guoyuan Xiong , Zhen Li , Jinfeng Zhang . Rapid and stable degradation of dichlorvos on chili pepper and histamine in sardines using S-scheme Al6Si2O13/g-C3N4 nanocomposites. Chinese Journal of Structural Chemistry, 2026, 45(5): 100867-100867. doi: 10.1016/j.cjsc.2026.100867
7. [7]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
8. [8]
  Lihui Ou , Zhancheng Liu , Dai-Huo Liu , Zhi Zhang . Cl-adsorbed Cu(111)/H₂O interface selectively realizes electrochemical CO₂ reduction towards C₂H₄ product: Mechanistic understanding. Chinese Chemical Letters, 2026, 37(2): 111920-. doi: 10.1016/j.cclet.2025.111920
9. [9]
  Shuang Zhao , Fei Jia , Kaibei Zhan , Rui-Xi Wang , Pengfei Tan , Lin Shen , Li-Ming Wu , Ling Chen . Amino substitution strategy achieves significant blue shift while preserving high optical anisotropy: A₂(H₃C₃N₄S₂)₂•H₂O (A =NH₄, K, Rb, Cs). Chinese Chemical Letters, 2026, 37(3): 110625-. doi: 10.1016/j.cclet.2024.110625
10. [10]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(Ⅵ) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-0. doi: 10.3866/PKU.WHXB202309020
11. [11]
  Jiaming Li , Yuxin Huang , Chengshan Zhao , Kai Wang . Unveiling the interfacial charge dynamics in organic/inorganic C3N4/Bi2O3 S-scheme heterojunction for efficient solar-driven H2O2 synthesis. Chinese Journal of Structural Chemistry, 2026, 45(5): 100869-100869. doi: 10.1016/j.cjsc.2026.100869
12. [12]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . Molten Intermediate Transportation-Oriented Synthesis of Amino-Rich g-C₃N₄ Nanosheets for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-0. doi: 10.3866/PKU.WHXB202406021
13. [13]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C₃N₄ Photocatalyst for Highly-Efficient H₂O₂ Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005
14. [14]
  Zheng Liu , Yuqing Bian , Graham Dawson , Jiawei Zhu , Kai Dai . Rational constructing of Zn_0.5Cd_0.5S-diethylenetriamine/g-C₃N₄ S-scheme heterojunction with enhanced photocatalytic H₂O₂ production. Chinese Chemical Letters, 2025, 36(9): 111272-. doi: 10.1016/j.cclet.2025.111272
15. [15]
  Jiangli Sun , Chaohui Zhang , Yican Zhang , Chunhong Fu , Ruiheng Liang , Zhongzheng Hu , Ge Song , Minghua Zhou . Ag₃PO₄/g-C₃N₄ S-scheme heterojunction photoanode coupled with natural air diffusion electrode for efficient organic pollutants degradation and H₂O₂ generation. Chinese Chemical Letters, 2026, 37(5): 111839-. doi: 10.1016/j.cclet.2025.111839
16. [16]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
17. [17]
  Xiaodong Zhang , Bohui Xu , Deshuai Xiao , Xinyuan Zhang , Pifu Gong , Zheshuai Lin . From centrosymmetric CN3H6C6H5SO3 to non-centrosymmetric CN3H6C6H4SO3(OH): Hydroxyl introduced hydrogen bond reconstruction to realize strong second harmonic generation. Chinese Journal of Structural Chemistry, 2025, 44(10): 100707-100707. doi: 10.1016/j.cjsc.2025.100707
18. [18]
  Yi-Chang Yang , Rui-Xi Wang , Li-Ming Wu , Ling Chen . Regulating the coplanarity of π-conjugated units through hydrogen bonding in FAHC2O4 and FAH2C3N3S3 crystals. Chinese Journal of Structural Chemistry, 2025, 44(10): 100714-100714. doi: 10.1016/j.cjsc.2025.100714
19. [19]
  Mengru , Qu , Chuanzhi Sun , Shujuan Jiang , Shaoqing Song . Localized Co3O4/In2S3 S-scheme heterojunction by polarization engineering for achieving an exceptional H2 efficiency. Chinese Journal of Structural Chemistry, 2026, 45(5): 100870-100870. doi: 10.1016/j.cjsc.2026.100870
20. [20]
  Piao Tang , Xin Wen , Jindong Chen , Ning Ye , Guang Peng . Ag(Te2O3)(PO4): The first Ag-containing phosphate-tellurite non-linear optical crystal featuring novel zigzag layered structure. Chinese Journal of Structural Chemistry, 2026, 45(1): 100763-100763. doi: 10.1016/j.cjsc.2025.100763