Citation:
Wu Jiong XIA, De Run LI, Yong Qiang TU, Ao Cheng CAO. An Efficient Synthetic Method of 11,12-Dihydroxyl Eudesmanolide Sesquiterpenoid from α-Santonin[J]. Chinese Chemical Letters,
;2001, 12(1): 21-24.
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A short and efficient procedure for introduction of tertiary hydroxyl to C-11 of eudesmanolide based on the rearrangement-oxidation of the exocylic double bond has been developed, which is synthetically valuable for a series of natural eudesmanolide sesquiterpenoids containing the 11,12-diol.
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Keywords:
- Introduction,
- tertiary hydroxyl,
- rearrangement-oxidation.
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