Citation: You Mao SHI, Shi Wei Lu, He Fu GUO, Ning Hai HU. THE CLEAVAGE REACTION OF Mo≡Mo TRIPLE BOND.SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF [CpMo(CO)₂(N,S-C₉H₆NS)]·O=PPh₃[J]. Chinese Chemical Letters, ;1992, 3(8): 665-666. shu

THE CLEAVAGE REACTION OF Mo≡Mo TRIPLE BOND.SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF [CpMo(CO)₂(N,S-C₉H₆NS)]·O=PPh₃

a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Delian 116023;
b Changchun Institute of Applied Chenistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 10 March 1992

Fund Project: This work was partly supported by Fuzhou Laboratory of Structural Chemistry, Academia Sinica.

The reaction of [CpMo(CO)₂]₂ with 8,8'-diquinolyl disulphide C₉H₆NSSNC₉H₆ resulted in the cleavage of Mo≡Mo triple bond to give a new mononuclear complex CpMo(CO)₂(N,S-C₉H₆NS) which was refluxed with PPh₃ in THF to form the title complex.The crystal structure of the title complex was determined by X-ray diffraction.
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18. [18]
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19. [19]
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20. [20]
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