Citation: Lu NENG, Jing Fu LIU. SYNTHESIS AND ¹⁸³W NMR CHARACTERIZATI0N OF α-[P₂W₁₅)O₆₂Ti₃]^12- HFTEROPOLYANION[J]. Chinese Chemical Letters, ;1994, 5(6): 547-548. shu

SYNTHESIS AND ¹⁸³W NMR CHARACTERIZATI0N OF α-[P₂W₁₅)O₆₂Ti₃]^12- HFTEROPOLYANION

Lu NENG ,
Jing Fu LIU

Department of Chemistry, Northeast Normal University, Changchun 130024

Received Date: 8 April 1994

A trisubstituted Dawson anion with tetravalent heteroelement titanium has been synthesized from the lacunary precursor Na₁₂[α-P₂W₁₅O₅₆].24H₂O and characterized by IR.UV.and ¹⁸³W NMR spectnm.¹⁸³W NMR of the title anion consists of three lines (intensity ratio 1:2:2) as expected for the trisubstituted α-Dawson anion.
1. [1]
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16. [16]
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18. [18]
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19. [19]
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20. [20]
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