Citation: Yan Bing ZU, Pei Fang LIU, Chuan Sin CHA, Xi LI. Investigation of the Interaction between Nafion and Several Trisbipyridyl Complexes by Spectroscopic Method[J]. Chinese Chemical Letters, ;1997, 8(4): 357-360. shu

Investigation of the Interaction between Nafion and Several Trisbipyridyl Complexes by Spectroscopic Method

Department of Chemistry, Wuhan university, Wuhan 430072

Received Date: 29 May 1996

Fund Project: The authors are grateful to the National Natural Science Foundation of China for financial support, financial support.

In this paper,evidences of strong interaction between several tris-bipyridyl complexes and Nafion matrix are provided by UV-VIS and FTIR spectra.The studied counterions also show electrosiatic interaction with the bonded -SO₃^- groups,as indicated by the shifting of γ_Sso₃^- to lower wave number.The most probable location of these complexes seems to be near the interface between the fluorocarbon back bone and the ionic cluster region.
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