Citation: Hong XUE, Yong An XU, Bin YU, Lian Xun GAO, Meng Xian DING. Helix-Sense-Selective Polymerization of N,N-Diphenyl (Meth) acrylamide by Anionic Catalysts[J]. Chinese Chemical Letters, ;2002, 13(7): 678-680. shu

Helix-Sense-Selective Polymerization of N,N-Diphenyl (Meth) acrylamide by Anionic Catalysts

State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 12 October 2001

In this paper, the helix-sense-selective polymerization of N,N-diphenyl acrylamide (DPAA) and N,N-diphenyl methacrylamide (DPMAA) were studied with living helix prepolymer as anionic initiator, and the chiral optical properties of the obtained polymers were investigated too.It was shown that optically active polymers of DPAA and DPMAA could be obtained under the experimental condition, and exhibited the same screw sense as that of the prepolymer.
- Helix-sense-selective polymerization,
- N,N-diphenyl (meth)acrylamide,
- specific rota-tion
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