Citation: Shi Ming DONG, Hui Zhu HE, Lin Zhi HU, Jian Min RON, Duo Yuan WANG. THE SYNTHESIS AND CHARACTERIZATION OF ASYMMETRIC TRIPYRRANE-CONTAINING MACROCYCLES[J]. Chinese Chemical Letters, ;1992, 3(1): 19-22. shu

THE SYNTHESIS AND CHARACTERIZATION OF ASYMMETRIC TRIPYRRANE-CONTAINING MACROCYCLES

Jnstitute of Photogrsphic Chemistry, Academia Sinica, Beijing 100101

Received Date: 9 September 1991

Fund Project: we would like to thank Miss.Yefeng YANG and Mr Mingguo ZHANG, Bui LL Wenpong YAN for eynthesis of 3, 4-diethypyrrole and benzyl 5-(acetoxymethyl)-3-methyl-4-ethylpyrrole-2-carboxylate.

An improved procedure was used to prepare the asymmetric tripyrrane-containing macrocycles,The yield was over 85% These maerocycles could be oxidized to the methine bridled 22 π electron aromatic cadmium (Ⅱ)complexes by reating with cadmium chloride in the presence of air and their structures were characterized.
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