Citation: Jun Min ZHU, Wei Xiao CAO, Xin De FENG. The Mechanism of the Initial Dark Oxidation of Ethers and the Ether-Oxygen Contact Charge Transfer Complex[J]. Chinese Chemical Letters, ;1997, 8(10): 869-872. shu

The Mechanism of the Initial Dark Oxidation of Ethers and the Ether-Oxygen Contact Charge Transfer Complex

College of Chemistry and Molecular Engineering, Peking University, Beijing 100871

Received Date: 23 June 1997

Fund Project: Project (29374151) supported by National Natural Science Foundation of China.

The contact charge transfer (CCT) absorption spectra of isopropyl ether,phenyl isopropyl ether and benzyl isopropyl ether with oxygen were measured.The mechanism of the initial dark oxidation of different ethers via ether-O₂ CCT was proposed.
1. [1]
  Xiang Li , Beibei Zhang , Zhixiang Wang , Xiangyu Chen . Organocatalyzed iodine-mediated reversible-deactivation radical polymerization via photoinduced charge transfer complex catalysis. Chinese Chemical Letters, 2025, 36(6): 110383-. doi: 10.1016/j.cclet.2024.110383
2. [2]
  Yan Zhao , Zhenming Tian , Qisen Jia , Ting Yao , Jiashu Li , Yanan Wang , Xuejing Cui , Jing Liu , Xin Chen , Luhua Jiang . Crystal orientation dependent charge transfer dynamics and interfacial water configuration boosting photoelectrocatalytic water oxidation to H2O2. Chinese Journal of Structural Chemistry, 2025, 44(7): 100619-100619. doi: 10.1016/j.cjsc.2025.100619
3. [3]
  Bowen Song , Chenxu Shi , Yinghao Qu , Hongjun Liu , Hui Yang , Xiaoming Wu , Xijun Liu . The electrical properties and charge transport mechanism of MXenes. Chinese Chemical Letters, 2025, 36(6): 110823-. doi: 10.1016/j.cclet.2025.110823
4. [4]
  Xianghua Zeng , Weichen Meng , Xiaochun Han , Jiachen Yang , Kaiqi Wu , Fengxian Gao , Xiliang Luo . Highly stable and antifouling solid-contact ion-selective electrode for K⁺ detection in complex system based on multifunctional peptide and conductive MOF. Chinese Chemical Letters, 2025, 36(8): 110564-. doi: 10.1016/j.cclet.2024.110564
5. [5]
  Feng Zhao , Hongyu Ding , Ting Sun , Chao Shen , Zu-Li Wang , Wei Wei , Dong Yi . Visible-light-promoted multi-component carbene transfer reactions of diazo compounds via ring-opening of cyclic ethers. Chinese Chemical Letters, 2026, 37(2): 111834-. doi: 10.1016/j.cclet.2025.111834
6. [6]
  Lin Zhang , Jianlong Li , Maoyuan Hu , Yao Xu , Xiaoli Xiong , Zhaoyu Jin . MOF-derived beaded stream-like nitrogen and phosphorus-codoped carbon-coated Fe₃O₄ nanocomposites via lattice-oxygen-mediated mechanism for efficient water oxidation. Chinese Chemical Letters, 2025, 36(8): 111123-. doi: 10.1016/j.cclet.2025.111123
7. [7]
  Xia Chen , Ting Dai , Meng-Ying Yin , Xing-Yuan Xia , Qiu-Ju Xing , Lei Tian , Jian-Ping Zou . Enhanced anodic mass transfer enables interfacial Cl^• for efficient ammonia oxidation. Chinese Chemical Letters, 2026, 37(3): 111445-. doi: 10.1016/j.cclet.2025.111445
8. [8]
  Ting Zhang , Baojing Huang , Hong Huang , Ailing Yan , Shiqiang Lu , Xufang Qian . Visible light boosted Fenton-like reaction of carbon dot-Fe(Ⅲ) complex: Kinetics and mechanism insights. Chinese Chemical Letters, 2025, 36(11): 110885-. doi: 10.1016/j.cclet.2025.110885
9. [9]
  Yihu Ke , Shuai Wang , Fei Jin , Guangbo Liu , Zhiliang Jin , Noritatsu Tsubaki . Charge transfer optimization: Role of Cu-graphdiyne/NiCoMoO4 S-scheme heterojunction and Ohmic junction. Chinese Journal of Structural Chemistry, 2024, 43(12): 100458-100458. doi: 10.1016/j.cjsc.2024.100458
10. [10]
  Junqing Ye , Mengyuan Ren , Junfeng Qian , Xibao Li , Qun Chen . Advances in graphene quantum dots-based photocatalysts for enhanced charge transfer in photocatalytic reactions. Chinese Chemical Letters, 2025, 36(9): 110857-. doi: 10.1016/j.cclet.2025.110857
11. [11]
  Hongchao Wang , Wei Hao , Haowei Wu , Qianyu Ding , Yu Wei , Hu Zhao , Shuzhou Li , Hanying Li , Jia Zhu . Rational design of n-type organic thermoelectric materials: Insights from C_nBTBT–F_mTCNQ charge-transfer complexes. Chinese Chemical Letters, 2026, 37(2): 111933-. doi: 10.1016/j.cclet.2025.111933
12. [12]
  Zhiqiang Wang , Yajie Gao , Tianjun Wang , Wei Chen , Zefeng Ren , Xueming Yang , Chuanyao Zhou . Photocatalyzed oxidation of water on oxygen pretreated rutile TiO₂(110). Chinese Chemical Letters, 2025, 36(4): 110602-. doi: 10.1016/j.cclet.2024.110602
13. [13]
  Bingkun Huang , Zelin Wu , Jing Zhang , Yanbiao Shi , Chuan-Shu He , Zhaokun Xiong , Bo Lai . Is the choice of quencher appropriate for exploring reactive oxygen species in advanced oxidation processes?. Chinese Chemical Letters, 2026, 37(3): 111537-. doi: 10.1016/j.cclet.2025.111537
14. [14]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Boosting bulk charge transport of CuWO4 photoanodes via Cs doping for solar water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100207-100207. doi: 10.1016/j.cjsc.2023.100207
15. [15]
  Jian Peng , Yue Jiang , Shuangyu Wu , Yanran Cheng , Jingyu Liang , Yixin Wang , Zhuo Li , Sijie Lin . A nonradical oxidation process initiated by Ti-peroxo complex showed high specificity toward the degradation of tetracycline antibiotics. Chinese Chemical Letters, 2024, 35(5): 108903-. doi: 10.1016/j.cclet.2023.108903
16. [16]
  Huanyu Liu , Gang Yu , Ruoyao Guo , Hao Qi , Jiayin Zheng , Tong Jin , Zifeng Zhao , Zuqiang Bian , Zhiwei Liu . Direct identification of energy transfer mechanism in Ce^Ⅲ-Mn^Ⅱ system by constructing molecular heteronuclear complexes. Chinese Chemical Letters, 2025, 36(2): 110296-. doi: 10.1016/j.cclet.2024.110296
17. [17]
  Jieqiong Xu , Wenbin Chen , Shengkai Li , Qian Chen , Tao Wang , Yadong Shi , Shengyong Deng , Mingde Li , Peifa Wei , Zhuo Chen . Organic stoichiometric cocrystals with a subtle balance of charge-transfer degree and molecular stacking towards high-efficiency NIR photothermal conversion. Chinese Chemical Letters, 2024, 35(10): 109808-. doi: 10.1016/j.cclet.2024.109808
18. [18]
  Xiao Yu , Dongyue Cui , Mengmeng Wang , Zhaojin Wang , Mengzhu Wang , Deshuang Tu , Vladimir Bregadze , Changsheng Lu , Qiang Zhao , Runfeng Chen , Hong Yan . Boron cluster-based TADF emitter via through-space charge transfer enabling efficient orange-red electroluminescence. Chinese Chemical Letters, 2025, 36(3): 110520-. doi: 10.1016/j.cclet.2024.110520
19. [19]
  Manlin Lu , Sheng Liao , Jiayu Li , Zidong Yu , Ningjiu Zhao , Zuoti Xie , Shunli Chen , Li Dang , Ming-De Li . Face-to-face π-π interactions and electron communication boosting efficient reverse intersystem crossing in through-space charge transfer molecules. Chinese Chemical Letters, 2025, 36(6): 110066-. doi: 10.1016/j.cclet.2024.110066
20. [20]
  Fengzhi Wang , Ke Hu , Jinquan Chen , Zhubin Hu , Haitao Sun , Tony D. James , Yufang Xu , Xuhong Qian . Meta-amino substituted naphthalimides exhibit large charge transfer and strong N-H vibrations enabling use as ratiometric fluorescent probe. Chinese Chemical Letters, 2026, 37(1): 110971-. doi: 10.1016/j.cclet.2025.110971

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1404)
HTML views(56)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return