Citation: Yin Sheng WU, Zheng Yu ZHOU, Ai Ping FU. THE CALCULATION OF RATE CONSTANT OF ELECTRON TRANSFER REACTION AT ELECTRODES[J]. Chinese Chemical Letters, ;1995, 6(1): 59-62. shu

THE CALCULATION OF RATE CONSTANT OF ELECTRON TRANSFER REACTION AT ELECTRODES

Chemistry Department, Qufu Normal University, Qufu, 273165

Received Date: 13 June 1994

Fund Project: This work was supported by the National Natural Science Foundation of Chinese Government.

After the electron transfers from the metal electrode to the Fe³⁺(H₂O)₆ ion,the free energy of activation of this electron transfer reaction is calculated,then using the transition probability which is calculated by the perturbed degeneration theory and the Fermi golden rule,the rate constant is gotten.Compared with the experimental results,it is satisfactory.
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