Citation: Jin Chang DING, Hua Yue WU. Chemoselective Reduction of Azides to Amines Using Sm/TMSCl System in the Presence of Trace Amounts of Water[J]. Chinese Chemical Letters, ;2001, 12(8): 659-662. shu

Chemoselective Reduction of Azides to Amines Using Sm/TMSCl System in the Presence of Trace Amounts of Water

Department of Chemistry, Wenzhou Normal College, Wenzhou 325027

Received Date: 1 February 2001

Azides can be easily reduced to the corresponding amines with Sm/TMSCl/H₂O (trace) system in excellent yields under mild and neutral conditions.
- Azides,
- amines,
- Sm/TMSCl/H₂O (trace) system.
1. [1]
  Chong-Yang Shi , Jian-Xing Gong , Zhen Li , Chao Shu , Long-Wu Ye , Qing Sun , Bo Zhou , Xin-Qi Zhu . Gold-catalyzed intermolecular amination of allyl azides with ynamides: Efficient construction of 3-azabicyclo[3.1.0] scaffold. Chinese Chemical Letters, 2025, 36(2): 109895-. doi: 10.1016/j.cclet.2024.109895
2. [2]
  Xin Li , Jia-Min Lu , Bo Li , Chen Zhao , Bei-Bei Yang , Li Li . Chiroptical sensing for remote chiral amines via a C–H activation reaction. Chinese Chemical Letters, 2025, 36(5): 110310-. doi: 10.1016/j.cclet.2024.110310
3. [3]
  Wen-Tao Ouyang , Jun Jiang , Yan-Fang Jiang , Ting Li , Yuan-Yuan Liu , Hong-Tao Ji , Li-Juan Ou , Wei-Min He . Sono-photocatalytic amination of quinoxalin-2(1H)-ones with aliphatic amines. Chinese Chemical Letters, 2024, 35(10): 110038-. doi: 10.1016/j.cclet.2024.110038
4. [4]
  Xin-Han Wang , Ying Huang , Chun-Lin Zhang , Song Ye . γ-C(sp³)-H acylation of aliphatic amines enabled by cooperative photoredox NHC/Pd catalysis. Chinese Chemical Letters, 2026, 37(5): 111484-. doi: 10.1016/j.cclet.2025.111484
5. [5]
  Yuan Zhang , Shenghao Gong , A.R. Mahammed Shaheer , Rong Cao , Tianfu Liu . Plasmon-enhanced photocatalytic oxidative coupling of amines in the air using a delicate Ag nanowire@NH₂-UiO-66 core-shell nanostructures. Chinese Chemical Letters, 2024, 35(4): 108587-. doi: 10.1016/j.cclet.2023.108587
6. [6]
  Jun Zhang , Zhiyao Zheng , Can Zhu . Stereochemical editing: Catalytic racemization of secondary alcohols and amines. Chinese Chemical Letters, 2024, 35(5): 109160-. doi: 10.1016/j.cclet.2023.109160
7. [7]
  Shan Wang , Ya-Jian Hu , Xuan Deng , Guang-Yi Zhang , Zichen Xu , Yu-Tao He . Visible light-mediated syntheses of β-pyridyl azides via three-component radical relay. Chinese Chemical Letters, 2026, 37(4): 111276-. doi: 10.1016/j.cclet.2025.111276
8. [8]
  Yubang Li , Xixi Hu , Daiqian Xie . The microscopic formation mechanism of O + H2 products from photodissociation of H2O. Chinese Journal of Structural Chemistry, 2024, 43(5): 100274-100274. doi: 10.1016/j.cjsc.2024.100274
9. [9]
  Xiuhua Wang , Jianrong Steve Zhou . A dicationic nickel complex-catalyzed asymmetric synthesis of chiral benzylic amines: Evolution from reductive amination to borrowing hydrogen reaction. Chinese Chemical Letters, 2026, 37(2): 111148-. doi: 10.1016/j.cclet.2025.111148
10. [10]
  Dongke Zhang , Li-Ao Ding , Qiuyu Xiang , Zhuojun Li , Qian Wu . P^Ⅲ/P^Ⅴ-catalytic platform enabling N-fluoro-thiocarbonylation of diaryl amines for modular synthesis of tertiary N-trifluoromethylamines. Chinese Chemical Letters, 2026, 37(5): 111461-. doi: 10.1016/j.cclet.2025.111461
11. [11]
  Xiaoya Zhuo , Xiangwen Tan , Yi Wang , Wanqing Wu , Huanfeng Jiang . Palladium catalyzed tandem Heck/Tsuji-Trost and 6-endo cyclization reactions of aryl iodides, vinylacetic acid, and aryl amines. Chinese Chemical Letters, 2026, 37(6): 111777-. doi: 10.1016/j.cclet.2025.111777
12. [12]
  Lihui Ou , Zhancheng Liu , Dai-Huo Liu , Zhi Zhang . Cl-adsorbed Cu(111)/H₂O interface selectively realizes electrochemical CO₂ reduction towards C₂H₄ product: Mechanistic understanding. Chinese Chemical Letters, 2026, 37(2): 111920-. doi: 10.1016/j.cclet.2025.111920
13. [13]
  Xuan Pang , Leyan Nian , Yongzhang Wang , Chunmei Huang . Na2(C6H4NO3)2∙H2O: A promising ultraviolet nonlinear optical crystal with strong second-harmonic generation effect and large birefringence. Chinese Journal of Structural Chemistry, 2026, 45(4): 100847-100847. doi: 10.1016/j.cjsc.2025.100847
14. [14]
  Xin Li , Wanting Fu , Ruiqing Guan , Yue Yuan , Qinmei Zhong , Gang Yao , Sheng-Tao Yang , Liandong Jing , Song Bai . Nucleophiles promotes the decomposition of electrophilic functional groups of tetracycline in ZVI/H₂O₂ system: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(10): 109625-. doi: 10.1016/j.cclet.2024.109625
15. [15]
  Jiaxin Zhang , Yingzhang Shi , Zhiwen Wang , Yujie Song , Dongpeng Yan . Photosynthesis of CH4 and H2O2 from CO2 and H2O over Pd/SnNb2O6 via strong metal-support interaction. Chinese Journal of Structural Chemistry, 2026, 45(5): 100866-100866. doi: 10.1016/j.cjsc.2026.100866
16. [16]
  Xia Jiang , Yan-Xin Chen , Rui Chen , Hao-Yan Shi , Ke-Xian Li , Wen-Ya Zhong , Jian-Feng Li , Can-Zhong Lu . Thermo-photocatalytic CO₂ conversion with H₂O to C₂ products in a continuous process by ZIF-67/biochar composites. Chinese Chemical Letters, 2026, 37(4): 111781-. doi: 10.1016/j.cclet.2025.111781
17. [17]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-0. doi: 10.3866/PKU.WHXB202312007
18. [18]
  Shuang Zhao , Fei Jia , Kaibei Zhan , Rui-Xi Wang , Pengfei Tan , Lin Shen , Li-Ming Wu , Ling Chen . Amino substitution strategy achieves significant blue shift while preserving high optical anisotropy: A₂(H₃C₃N₄S₂)₂•H₂O (A =NH₄, K, Rb, Cs). Chinese Chemical Letters, 2026, 37(3): 110625-. doi: 10.1016/j.cclet.2024.110625
19. [19]
  Jie Wang , Jijie Zhang , Defang Ma , Zhenxiang Sun , Yan Wang , Qinyan Yue , Yanwei Li , Yue Gao , Baoyu Gao , Xing Xu . Simultaneous removal of tetracycline and antibiotic resistant bacteria/genes in UV-LED/H₂O₂ system: Competitive interactions and wavelength dependence. Chinese Chemical Letters, 2026, 37(2): 111209-. doi: 10.1016/j.cclet.2025.111209
20. [20]
  Junjie Wang , Shulin Gao , Sujuan Hu . Zinc-air battery-H₂O₂ generation system: Current progress, key challenges, optimization strategies and future developments. Chinese Chemical Letters, 2026, 37(6): 111000-. doi: 10.1016/j.cclet.2025.111000

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1597)
HTML views(65)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return