Citation: Rui Fang SONG, Fei LI, Guang Min LIU, You Gang MAO, Fei DU. THE STUDY OF STRUCTURE AND DYNAMICS OF DINUCLEAR COMPLEXES [Mo(VI)]₂-EGTA AND [Mo(VI)]₂-EGTA BY ¹HNMR[J]. Chinese Chemical Letters, ;1996, 7(6): 567-568. shu

THE STUDY OF STRUCTURE AND DYNAMICS OF DINUCLEAR COMPLEXES [Mo(VI)]₂-EGTA AND [Mo(VI)]₂-EGTA BY ¹HNMR

Key Laboratory for Molecular Spectra & Structure. Institute of Theoretical Chemistry, Jilin University, Changchun. 130023

Received Date: 18 September 1995

The ¹H and ¹³C NMR spectra of the dinuclear complexes of molybdenum (Ⅵ) with ethylenediaminetetraacetic acid ([Mo(VI)]₂-EDTA) and 3,12-bis(carboxymethyl)-6,9-dioxa-3,12-diazatetra-decanedioic acid([Mo(VI)]₂-EGTA) at various temperatures were measured.The solution structure of the two dinuclear complexes was determined and the possible exchange process of the isomers is suggested.
1. [1]
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3. [3]
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5. [5]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
  Ruihu Wang , Aidang Lu . 新型铬(VI)检测试纸的制备及应用——介绍一个应用化学综合实验. University Chemistry, 2025, 40(8): 284-290. doi: 10.12461/PKU.DXHX202410102